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二苯醚类化合物的相转移催化合成研究
引用本文:谭平. 二苯醚类化合物的相转移催化合成研究[J]. 湖南文理学院学报(自然科学版), 2004, 16(2): 12-13
作者姓名:谭平
作者单位:湖南机电职业技术学院,湖南,津市,415400
摘    要:以亲核取代反应活性较小的单硝基氯苯和取代苯酚为原料,利用超声波辐射和相转移催化相结合的方法,成功合成了9种二苯醚类化合物,并对反应条件进行了考察.本法反应快,条件温和,操作简便,展示了超声波技术在有机合成上的广泛应用前景,对于改进二苯醚的合成条件及研究芳香化合物的亲核取代应有一定的参考价值.

关 键 词:二苯醚  超声波  相转移催化  合成
文章编号:1672-6146(2004)02-0012-02
修稿时间:2004-02-16

Studies on the synthesis of application of phase thansfer catalysis in Diphenyl Oxide compounds
TAN Ping. Studies on the synthesis of application of phase thansfer catalysis in Diphenyl Oxide compounds[J]. Journal of Hunan University of Arts and Science:Natural Science Edition, 2004, 16(2): 12-13
Authors:TAN Ping
Abstract:By using mono mitro-chlrobenzene with less nucleo-philic substitution reactivity and substituted benzenol and ultrasound irradiation and PTC(Phase Transfer Catalysis),9 kinds of diphenyl oxide compounds were syntheiszed and the reaction condition was examined.This methed can react quickly and process conventiently,besides,the reaction condition was mild.It showed a wide application-prospect of ultrasound technology in the field of organic synthesis.It had reference sense in improving the syrothesis condition of diphenyl oxide and also in studying nucleophilic substitution in aromatic compounds.
Keywords:diphenyl oxide  ultrasound  PTC(Phase Transfer Catalysis)  synthasis  
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