17β-Hydroxymethyl-Steroide: Darstellung von Derivaten des 17α-Hydroxy-17β-hydroxymethyl-4-androsten-3-ons |
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Authors: | A Schubert S Schwarz |
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Institution: | (1) Wissenschaftliche Laboratorien des VEB Jenapharm, Jena, DDR |
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Abstract: | Summary Starting from 17 -hydroxy-17 -hydroxymethyl-4-androsten-3-one, we synthesized 4-chloro-17 -hydroxy-17 -hydroxymethyl-4-androsten-3-one-17, 20-acetonide and 17 -hydroxy-17 -hydroxymethyl-1, 4-androstadien-3-one. 11 , 17 -dihydroxy-17 -hydroxymethyl-4-androsten-3-one was obtained from cortisone via methyl-17 -hydroxy-3, 11-dioxo-4-etienate. |
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