| (pph_3)_2pt[Sn_2(OH)_xCl_(4-x)](x=1,2,3,4)原子簇化合物的合成与结构研究 |
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| 引用本文： | 吴兴才,陈天朗. (pph_3)_2pt[Sn_2(OH)_xCl_(4-x)](x=1,2,3,4)原子簇化合物的合成与结构研究[J]. 安徽理工大学学报(自然科学版), 1989, 0(2) |
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| 作者姓名： | 吴兴才 陈天朗 |
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| 作者单位： | 四川大学化学系无机化学教研室 主任 |
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| 摘 要： | 本文报导通过Pt(pph_3)_4与SnCl_2·2H_2O反应合成四种新的铂锡簇化物,其化学式为(pph_3)_2pt[Sn_2(0H)_xCl_(4-x)](x=1,2,3,4)利用IR,UV,HNMR等对这些簇化物进行表征,并用VB理论对其结构进行预测,提出两种可能骨架结构:
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| 关 键 词： | 簇状化合物 铂 锡 合成 结构式 |
Investigations into Synthesis and Structure of Atomic Cluster Compounds (pph_3)_2pt[Sn_2(OH)_xCl_(4-x)](x=1,2,3,4) |
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| Wu Xingcai Chen Tianlang. Investigations into Synthesis and Structure of Atomic Cluster Compounds (pph_3)_2pt[Sn_2(OH)_xCl_(4-x)](x=1,2,3,4)[J]. Journal of Anhui University of Science and Technology:Natural Science, 1989, 0(2) |
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| Authors: | Wu Xingcai Chen Tianlang |
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| Affiliation: | Wu Xingcai Chen Tianlang |
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| Abstract: | Eour new Pt-Sn different-nuclear compounds are produced in the reaction of pt ( pph3 )4 with SnCl22H2O which are chemi-cally expressed as ( pph3 ) 2Pt[Sn2 (OH)xCl(4-x)] (x=1; 2; 3; 4 ) These cluster compounds are characterized by using IR; UV and HNMR and further predicted by using the V. B. Theory as of two possible skeleton structures: |
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| Keywords: | cluster compound platinum tin synthesis structural formula |
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