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Ferric perchlorate-promoted reaction of [60]fullerene with β-keto esters |
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| Authors: | FaBao Li SanE Zhu Xun You GuanWu Wang |
| Institution: | 1. Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, School of Chemistry and Chemical Engineering, Hubei University, Wuhan, 430062, China 2. Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemistry, University of Science and Technology of China, Hefei, 230026, China |
| Abstract: | The ferric perchlorate-promoted reaction of 60]fullerene (C60) with ethyl 2-methylacetoacetate generates fullerenyl hemiketal as a mixture of trans and cis isomers, while the reaction with ethyl acetoacetate gives a C60-fused dihydrofuran derivative. A possible reaction mechanism for the formation of these products is proposed. |
| Keywords: | [60]fullerene ferric perchlorate β-keto esters fullerenyl hemiketal C 60-fused dihydrofuran derivative |
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