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钙钛矿型系列化合物GdFe_(1-x)Cr_xO_3的水热合成及其性质表征
引用本文:乔宇,徐占林,赵丽娜,周莹.钙钛矿型系列化合物GdFe_(1-x)Cr_xO_3的水热合成及其性质表征[J].松辽学刊,2014(1):17-19.
作者姓名:乔宇  徐占林  赵丽娜  周莹
作者单位:[1]吉林师范大学环境友好材料制备与应用教育部重点实验室,吉林四平136000 [2]吉林师范大学化学学院,吉林四平136000
基金项目:吉林省教育厅"十二五"科学技术研究项目(吉教科合字[2013]第204号)
摘    要:用温和的水热法合成了具有钙钛矿型ABO3结构的系列化合物GdFe1-x Cr x O3,并对产物最终组成和磁性进行了分析.碱度在反应物中的多少直接控制着最终产物的组成,只有精确的控制碱度才能得到我们预期所需的化学计量比的产物.在合成方法上,水热法与固相法相比,前者能够得到更完美的、结晶度更好的晶体,合成有序度更高的材料.

关 键 词:水热法  Cr掺杂  磁性

Hydrothermal Synthesis and Characterization of Perovskite Type Compounds GdFe1-xCrxO3
QIAO Yu,XU Zhan-lin,ZHAO Li-na,ZHOU Ying.Hydrothermal Synthesis and Characterization of Perovskite Type Compounds GdFe1-xCrxO3[J].Songliao Journal (Natural Science Edition),2014(1):17-19.
Authors:QIAO Yu  XU Zhan-lin  ZHAO Li-na  ZHOU Ying
Institution:1. Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Ministry of Education, Jilin Normal University, Siping 136000, China ; 2. College of Chemistry, Jilin Normal University, Siping 136000, China)
Abstract:Perovskite type structure with ABO3 series of compound GdFe1-xCrxO3 was synthesized by hydrothermal method, by analyzing final product composition and magnetic properties. The alkalinity in the reactants in the direct control over the composition of final products, only theprecise control of alkalinity, we could obtain the expected stoichiometry product As for the synthesis method, hydrothermal method and solid-phase method, the former can be more perfect, the crystallization degree better, synthesis of ordered more material.
Keywords:hydrothermal method  Cr doping  magnetic properties
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