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煤的红外光谱研究
引用本文:刘国根,邱冠周,胡岳华. 煤的红外光谱研究[J]. 中南大学学报(自然科学版), 1999, 0(4)
作者姓名:刘国根  邱冠周  胡岳华
作者单位:中南工业大学测试分析中心
基金项目:国家教育部跨世纪人才基金
摘    要:利用740型傅里叶变换红外(FTIR)光谱仪系统地研究了褐煤与风化烟煤的红外光谱.结果表明:含碳量在一个较宽的范围内煤的红外光谱图相类似,从褐煤到烟煤,随着煤化作用的加强,脂肪族C—H伸缩振动峰逐渐减弱,褐煤中存在大量原生腐植酸,烟煤中则含有大量再生腐植酸,这将为判断烟煤是否风化提出又一判据.根据煤的红外光谱还可推测其所含腐植酸种类及含量.

关 键 词:煤;红外光谱;风化作用;腐植酸

STUDY ON INFRARED SPECTRA OF COALS
Liu Guogen Qiu Guanzhou Hu Yuehua. STUDY ON INFRARED SPECTRA OF COALS[J]. Journal of Central South University:Science and Technology, 1999, 0(4)
Authors:Liu Guogen Qiu Guanzhou Hu Yuehua
Abstract:In this paper, the infrared(IR) spectra from 4 000 to 400 cm -1 for brown and bituminou coal have been systematically studied by means of 740 model FTIR spectrometer. A similar basic skeleton for coals over a wide range of carbon content is indicated by the general similarity of the spectra. Due to the strengthening of coalification, the aliphatic C H stretching absorption bands of bituminous coal is weaker than that of brown coal. The brown coal contains a large amount of primary humic acid. The bituminous coal contains a large amount of regenerative humic acid, which will offer a standard for judging whether the coal was efflorescend. Humic acid type and content can be deduced by infrared spectra of coals.
Keywords:coal  IR spectra  efflorescence reaction  humic acid  
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