| 以碳酸钙为模板微波水热合成碳酸羟基磷灰石微球 |
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| 引用本文： | 朱万华,张群,汪小红,汪绪武. 以碳酸钙为模板微波水热合成碳酸羟基磷灰石微球[J]. 安庆师范学院学报(自然科学版), 2014, 0(3): 92-97 |
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| 作者姓名： | 朱万华 张群 汪小红 汪绪武 |
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| 作者单位： | 安庆师范学院功能配合物安徽省重点实验室,化学化工学院,安徽安庆246011 |
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| 摘 要： | 通过将碳酸钙微球浸入到磷酸氢二铵溶液中,并在60℃条件下进行微波水热处理,获得了直径约为1μm的羟基磷灰石微球,其转化机理为溶解-再沉淀反应。碳酸钙微球浸入到磷酸氢二铵溶液中后,在微波辅助作用下,钙离子从碳酸钙表面释放并与溶液中的磷酸根离子进行反应,获得了羟基磷灰石微球,该微球保持了起始球霰石的形状和尺寸。本研究为可控构象的磷灰石基生物材料的制备提供了简便而有效的方法。
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| 关 键 词： | 碳酸钙 前驱物 微波 羟基磷灰石 |
Hydrothermal Fabrication of Carbonated Hydroxyapatite Microspheres Using Similar Structured Hard-precursors with the Assistant of Microwave |
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| ZHU Wan-hua,ZHANG Qun,Wang Xiao-hong,WANG Xu-wu. Hydrothermal Fabrication of Carbonated Hydroxyapatite Microspheres Using Similar Structured Hard-precursors with the Assistant of Microwave[J]. Journal of Anqing Teachers College(Natural Science Edition), 2014, 0(3): 92-97 |
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| Authors: | ZHU Wan-hua ZHANG Qun Wang Xiao-hong WANG Xu-wu |
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| Affiliation: | ( Anhui Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering, Anqing Teachers College, Anqing 246011, China) |
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| Abstract: | Carbonated hydroxyapatite microspheres with a particle size of 1 μm have been fabricated hydrothennally by soaking calcium carbonate microspheres in a disodium hydrogen phosphate solution at 60℃. The transformation mechanism is a dissolutionprecipitation reaction. After soaking in the disodium hydrogen phosphate solution, the calcium ions released from the calcium carbonate microspheres react with phosphate ions in the solution to form carbonated hydroxyapatite nanopartieles, copying faithfully the shape and size of original vaterites, were fabricated under the assistance of microwave irradiation. The research may provide a feasible method for the fabrication of hydroxyapatite-hased biomaterials with controllable configuration. |
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| Keywords: | calcium carbonate precursors microwave hydroxyapatite |
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