| 四氮唑钴配合物的合成及结构表征 |
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| 引用本文： | 王依军,吴根华.四氮唑钴配合物的合成及结构表征[J].安庆师范学院学报(自然科学版),2014(3):98-101. |
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| 作者姓名： | 王依军 吴根华 |
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| 作者单位： | 安庆师范学院化学化工学院,安徽安庆246011 |
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| 基金项目： | 国家自然科学基金（21171008）资助. |
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| 摘 要： | 以四氮唑乙酸为原料,经schiff碱缩合反应合成酰腙配体。在常温下,通过溶剂挥发法制备配合物,其化学式为C18H14CoN14O2。利用CCD X-射线单晶衍射仪对配合物进行结构表征,结果表明此配合物为单核Co六配位,借助分子间氢键的弱作用力形成网络堆积结构。
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| 关 键 词： | 功能配合物 schiff碱 四氮唑 溶剂挥发法 单晶衍射 |
The Synthesis and Structure Characterization of Tetrazole Cobalt Complexes |
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| WANG Yi-Jun,WU Gen-Hua.The Synthesis and Structure Characterization of Tetrazole Cobalt Complexes[J].Journal of Anqing Teachers College(Natural Science Edition),2014(3):98-101. |
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| Authors: | WANG Yi-Jun WU Gen-Hua |
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| Institution: | (School of Chemistry and Chemical Engineering, Anqing Teachers College, Anqing 246011, China) |
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| Abstract: | With H-Tetrazole-1-acetic acid as main starting material, target product is an acyl hydrazone ligand which is prepared by Schiff base condensation. At room temperature, functional coordination compounds are made by solution method, and its chemical formula is ClSHl4CoN14O2. Coordination geometry is characterized by CCD X-ray single crystal diffraction instrument. The results show that a complex unit structure is the six ligand complexes of mononuclear Co, with the aid of intermolecular the weak force of hydrogen bonding form accumulation of network structure. |
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| Keywords: | functional coordination compound Schiff soda Tetrazole solution method single crystal diffraction |
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