| 2-(4-羟基苯氧基)丙酸乙酯的合成 |
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| 引用本文： | 卢莲英 王建强 郑静 杜志超 高小梅. 2-(4-羟基苯氧基)丙酸乙酯的合成[J]. 佳木斯大学学报, 2005, 23(2): 260-264 |
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| 作者姓名： | 卢莲英 王建强 郑静 杜志超 高小梅 |
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| 作者单位： | [1]湖北师范学院化学与环境工程系，湖北黄石435002 [2]湖北工业大学，湖北武汉430000 |
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| 摘 要： | 以L-乳酸乙酯为原料，经酰化、缩合反应合成了2-(4-羟基苯氧基)丙酸乙酯．实验主要考察了催化剂、反应温度与时间、原料配比、溶剂用量、碱用量等因素的影响，荻得了优化的反应条件，收率达90％以上．经红外光谱、质谱对合成的化合物进行了结构袁征。
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| 关 键 词： | 苯氧丙酸类除草剂 2-（4-羟基苯氧基）丙酸乙酯 合成 |
| 文章编号： | 1008-1402(2005)02-0260-05 |
| 修稿时间： | 2004-09-29 |
Synthesis of R- ( + ) -2- (4- Hydroxyphenoxy) Propionic Ester |
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| LU Lian-ying,WANG Jian-qiang,ZHENG Jing,DU Zhi-chao,GAO Xiao-mei. Synthesis of R- ( + ) -2- (4- Hydroxyphenoxy) Propionic Ester[J]. Journal of Jiamusi University(Natural Science Edition), 2005, 23(2): 260-264 |
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| Authors: | LU Lian-ying WANG Jian-qiang ZHENG Jing DU Zhi-chao GAO Xiao-mei |
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| Affiliation: | LU Lian-ying~1,WANG Jian-qiang~2,ZHENG Jing~1,DU Zhi-chao~1,GAO Xiao-mei~1 |
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| Abstract: | With L-Ethyl lactate acid, it was acylated to give L-Ethyl p-toluenesulfonyl lactate. And reacted with hydroquinone, R-(+)-2-(4-Hydroxyphenoxy) propyonic ester was gotten. We process the conditional test of catalyst, reaction temperature and time, molar ratio to reactants, solcent usage, the amounts of alkali, and explore a best technical condition. The yield was up to 90% and the structures of these compounds were identified by using IR and MS spectrum. |
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| Keywords: | R-Phenoxypropionate herbicide R-(+)-2-(4-Hydroxyphenoxy) propionic ester synthesis |
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