| 直线法研究Ni[i-(C_3H_7O)_2PS_2]_2与1,10-菲啰啉的加合反应 |
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| 引用本文： | 刘照文,贺敏强. 直线法研究Ni[i-(C_3H_7O)_2PS_2]_2与1,10-菲啰啉的加合反应[J]. 大庆师范学院学报, 2007, 0(5) |
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| 作者姓名： | 刘照文 贺敏强 |
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| 作者单位： | 宿迁学院材料科学与工程系 江苏宿迁223800(刘照文)，江苏大学化学化工学院 江苏镇江212003(贺敏强) |
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| 摘 要： | 用P2S5、i-C3H7OH和NiCl2.H2O为原料合成了(Ni[i-(C3H7O)2PS2]2),光谱法研究了它与1,10-菲啰啉的加合反应,并应用直线法确定此加合反应的稳定常数为8.24×107和加合物组成比为1∶2。
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| 关 键 词： | 1,10-菲啰啉 直线法 平衡常数 组成比 |
Studay on Adductive Reaction of Ni[i-(C_3H_7O)_2PS_2]_2 with 1,10-phenanthroline by Straight Line Method |
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| LIU Zhao-wen,HE Min-qiang. Studay on Adductive Reaction of Ni[i-(C_3H_7O)_2PS_2]_2 with 1,10-phenanthroline by Straight Line Method[J]. Journal of Daqing Normal University, 2007, 0(5) |
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| Authors: | LIU Zhao-wen HE Min-qiang |
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| Affiliation: | LIU Zhao-wen1,HE Min-qiang2 |
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| Abstract: | (Ni[i-(C3H7O)2PS2] 2)has been synthesized with P2S5,i-C3H7OH and NiCl2·H2O.The adductive reaction of Ni[i-(C3H7O)2PS2] 2 with 1,10-phenanthroline is studied by spectrophotometer method.By staight line method,stablity constants of the adductive reaction is 8.24×107,and composite ratio of the compound is 1∶2. |
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| Keywords: | 1 10-phen. straight line method equilibrium constant composite ratio |
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