| 几种气相烷烃自由基与分子Cl_2反应速率常数的ACM理论计算 |
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| 引用本文： | 奚正楷,杨明.几种气相烷烃自由基与分子Cl_2反应速率常数的ACM理论计算[J].济南大学学报(自然科学版),1990(3). |
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| 作者姓名： | 奚正楷 杨明 |
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| 作者单位： | 山东建材学院应用化学系，山东建材学院应用化学系 中国科学院大连化学物理研究所研究生院学习 |
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| 摘 要： | 本文运用ACM统计速率理论计算了甲基、乙基、异丙基、特丁基等四种烷烃自由基与分子Cl_2气相反应的速率常数及其随温度变化的关系。计算结果均与实验值接近,除甲基外,随温度变化的趋势也与实验结果大体一致。计算结果表明,该变化趋势在一定温度时发生转折。
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| 关 键 词： | 烷烃自由基 气相反应 速率常数 ACM理论 |
ACM THEORETICAL CALCULATION OF THE RATE CONSTANTS FOR THE REACTIONS OF SOME ALKYL RADICALS WITH MOLECULAR CHLORINE IN GAS PHASE |
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| Xi zhengkai et al.ACM THEORETICAL CALCULATION OF THE RATE CONSTANTS FOR THE REACTIONS OF SOME ALKYL RADICALS WITH MOLECULAR CHLORINE IN GAS PHASE[J].Journal of Jinan University(Science & Technology),1990(3). |
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| Authors: | Xi zhengkai |
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| Institution: | Xi zhengkai et al |
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| Abstract: | The rate constants and their temperature dependence for the gas reactions of methyl, ethyl, isopropyl and tert-butyl radicals with molecular chlorine have been calculated by using ACM statistical rate theory. Ths calculated results of rate constants are all closed to, and the temperature dependence are almost agreement with the experimental results except methyl. The calculated results showed that there is a turning point of temperature dependence at a certain degree. |
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| Keywords: | alkyl radical gas reaction rate constants ACM theory |
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