| 无限稀活度系数与选择性分子间引力 |
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| 引用本文： | 邓文杰,沈报恩,唐寅轩,应红雨.无限稀活度系数与选择性分子间引力[J].杭州师范学院学报(社会科学版),1991(3). |
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| 作者姓名： | 邓文杰 沈报恩 唐寅轩 应红雨 |
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| 作者单位： | 杭州师范学院化学系，杭州大学化学系，杭州大学化学系，丽水卫生学校 |
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| 摘 要： | 本文采用气相色谱法测定了十余种不同溶质在聚乙二醇-400和邻苯二甲酸二壬酯上的无限稀活度系数。应用“选择性分子间引力”的理论,对实验结果进行了理论探讨。
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| 关 键 词： | 无限稀活度系数 选择性分子间引力 |
THE INFINITE DILUTION ACTIVITY COEFFICIENTS AND SELECTIVE INTERMOLECULAR FORCE |
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| Deng Wenjie Shen Baoen Tang Yinxuan Ying Hongyu.THE INFINITE DILUTION ACTIVITY COEFFICIENTS AND SELECTIVE INTERMOLECULAR FORCE[J].Journal of Hangzhou Teachers College(Humanities and Social Sciences),1991(3). |
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| Authors: | Deng Wenjie Shen Baoen Tang Yinxuan Ying Hongyu |
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| Institution: | Deng Wenjie Shen Baoen Tang Yinxuan Ying Hongyu (Department of Chemistry) (Hang Zhou University) (Li Sui Hygiene School) |
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| Abstract: | The infinite dilution activity eoefficients of different solutes in polyethylene glycol-400 and dinonylphthalale have been measured by gas-liquid chromatography. The observed results show the presence of selective intermolecular force between the adaptable groups existing on the different compounds respectively.This paper gives a satisfactory explanation of the experimental results by the theory of the selective inlcrmolecular force, especially of those abnormal phenomena which cannot be interpreted by the common Van der waal's force. |
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| Keywords: | infinite dilution activity coefficients selective interniolecular force |
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