煤粉压力燃烧特性及动力学分析

利用加压热重分析天平,采用非等温燃烧方法对国内某钢铁厂高炉典型喷吹煤粉的燃烧特性及反应动力学参数进行了实验研究。研究了在0.1,1.1,2.1,3.1,4.1 MPa压力等级下试样煤粉的着火温度、最大燃烧速率温度、燃尽温度、综合燃烧特性指数(S)、最大燃烧速率等燃烧特征参数,计算了煤粉燃烧过程的活化能(E)和指前因子(A)。结果表明,北区煤粉在压力等级由0.1 MPa升至4.1 MPa的燃烧过程中,着火点温度最多下降了85.7K,失重峰值温度最多提前了249.3K,燃尽温度最多下降了375K,最大燃烧速率最多提升了10倍,燃烧特性指数最大为常压下的33.6倍;两段热解活化能和指前因子的对数值之间存在动力学补偿效应;煤粉的反应控制条件及燃烧方式转变的临界压力为3.1MPa。

Combustion characteristics and kinetic analysis of pulverized coal under different pressure grades

By using thermo gravimetric balance, experimental research on combustion characteristics and dynamics parameters of the typical coal injection from some domestic steelworks are conducted with non-isothermal method. The combustion characteristic parameters of the sample pulverized coal such as ignition temperature, peak temperature at maximum weight loss rate, burnout temperature, general burn exponent(S), and maximum combustion rate are studied under pressure grades of 0.1, 1.1, 2.1, 3.1 and 4.1 MPa, the activation energy (E) and pre-exponential factor in the combustion process are calculated. The results show that when the pressure increases from 0.1 to 4.1 MPa, ignition temperature decreases by 85.7 K at most, peak temperature at maximum weight loss rate decreases by 249.3 K at most, burnout temperature decreases by 375 K at most, maximum weight loss rate increases by 10 times, and S increases by 33.6 times at most. It is also shown that there exists a kinetic complementation between E and ln A from the view point of dynamics, and the critical pressure of pulverized coal reaction control requirement and combustion mode transform is 3.1 MPa for the pulverized coal.