| EXAFS研究合成甲醇催化剂Cu/ZnO/AL_2O_3的制备条件 |
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| 引用本文： | 沈百荣,方志刚,孙琦,范康年,邓景发.EXAFS研究合成甲醇催化剂Cu/ZnO/AL_2O_3的制备条件[J].复旦学报(自然科学版),1999(6). |
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| 作者姓名： | 沈百荣 方志刚 孙琦 范康年 邓景发 |
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| 作者单位： | 复旦大学化学系 |
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| 基金项目： | 国家自然科学基金!29892167，国家自然科学基金!29673014 |
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| 摘 要： | 用EXAFS研究了不同制备条件对合成甲醇催化剂Cu／ZnO／Al2O3结构的影响，研究表明选择较温和的还原气氛和还原温度有利于制备高分散的Cu催化剂，在还原前较小的焙烧温度有利于制备较小颗粒的ZnO粒子，此研究表明Cu0是催化剂的主要活性组分．
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| 关 键 词： | EXAFS 甲醇合成 Cu／ZnO／Al_2O_3 催化剂制备 |
EXAFS Study on the Preparation of Cu/ZnO/Al_2O_3 Catalyst for Methanol Synthesis |
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| SHEN Bai-rong, FANG Zhi-gang, SUN Qi, FAN Kang-nian, DENG Jing-fa.EXAFS Study on the Preparation of Cu/ZnO/Al_2O_3 Catalyst for Methanol Synthesis[J].Journal of Fudan University(Natural Science),1999(6). |
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| Authors: | SHEN Bai-rong FANG Zhi-gang SUN Qi FAN Kang-nian DENG Jing-fa |
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| Institution: | Department of Chemistry |
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| Abstract: | The effect of different preparation condition on the structure of Cu/ZnO/Al2O, catalyst for methanol synthesis has been studied by EXAFS. The result show that moderate reduction gas and reduction temperature is preferable to the preparation of copper catalyst with high dispersion. Relatively low calcining temperature is beneficial to get small size ZnO particle. This research confirmed that Cu0 should be the active site of the catalyst. |
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| Keywords: | EXAFS methanol synthesis Cu/ZnO/Al_2O_3 preparation of catalyst |
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