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微波辐照对酯化反应的作用机理
引用本文:李少君,李峰,何静,孙鹏,段雪,王作新. 微波辐照对酯化反应的作用机理[J]. 北京化工大学学报(自然科学版), 1996, 0(4)
作者姓名:李少君  李峰  何静  孙鹏  段雪  王作新
作者单位:北京化工大学应用化学系
摘    要:通过乙二醇单乙醇和醋酸的酯化反应,研究了微波辐照对酯化反应的作用机理.利用微波辐照与常规加热两种方法,对介质回流温度前后两个阶段反应的结果作了对比,从而得出微波对酯化反应有明显的加速作用,其加速作用实质是提高反应介质的升温速率.在实验条件下,微波提供给反应体系的能量是热能.

关 键 词:微波辐照;酯化反应;机理

Mechanism of Esterification Irradiated by Microwave
Li Shaojun,Li Feng,He Jing,Sun Peng,Duan Sue,Wang Zuoxin. Mechanism of Esterification Irradiated by Microwave[J]. Journal of Beijing University of Chemical Technology, 1996, 0(4)
Authors:Li Shaojun  Li Feng  He Jing  Sun Peng  Duan Sue  Wang Zuoxin
Abstract:The mechanism of esterification irradiated by microwave was studied by using the synthetization system of 2-Ethoxycthyl acetate with the catalyst of H2SO4 Compared the irradiation by microwave to the conventional heating, it was demonstrated that the rate of esterification of 2-Ethoxyethyl Acetate had been obviously accelerated by microwave due tO raising the rate of increase in temperature since microwave;upplied a great amount of heat energy to the reaction system.
Keywords:microwave irradiation  esterification  mechanism.
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