| 1-吡啶甲酰基-4-烯丙基氨基硫脲的合成与结构表征 |
| |
| 引用本文： | 赵明根,石玉芳,赵江瑜,吕海斌,张婷婷.1-吡啶甲酰基-4-烯丙基氨基硫脲的合成与结构表征[J].山西大学学报(自然科学版),2007,30(1):64-67. |
| |
| 作者姓名： | 赵明根 石玉芳 赵江瑜 吕海斌 张婷婷 |
| |
| 作者单位： | 忻州师范学院,化学系,山西,忻州,034000 |
| |
| 基金项目： | 山西省教育厅资助项目;忻州师院基金 |
| |
| 摘 要： | 报道了1-吡啶甲酰基-4-烯丙基氨基硫脲的合成.以3-溴丙烯和硫氰酸铵制得异硫氰酸烯丙酯(1);将2-吡啶甲酸,3-吡啶甲酸和4-吡啶甲酸酯化;由酯化反应所得(3a-3c)经肼解得吡啶甲酰肼(4a-4c);最后将化合物(1)分别和4a,4b,4c反应,合成了1-吡啶甲酰基-4-烯丙基氨基硫脲类化合物(5a-5c),其结构经红外光谱、氢核磁共振谱、元素分析表征.
|
| 关 键 词： | 1-吡啶甲酰基-4-烯丙基氨基硫脲 烯丙基氨基硫脲 合成 |
| 文章编号： | 0253-2395（2007）01-0064-04 |
| 修稿时间： | 2006-05-122006-09-11 |
Synthesis and Structure Characterization of 1-Pridineformyl-4-allylaminothiourea |
| |
| ZHAO Ming-gen,SHI Yu-fang,ZHAO Jiang-yu,Lü Hai-bin,ZHANG Ting-ting.Synthesis and Structure Characterization of 1-Pridineformyl-4-allylaminothiourea[J].Journal of Shanxi University (Natural Science Edition),2007,30(1):64-67. |
| |
| Authors: | ZHAO Ming-gen SHI Yu-fang ZHAO Jiang-yu Lü Hai-bin ZHANG Ting-ting |
| |
| Abstract: | Three new thiourea derivatives containing allyl and pyridinoyl(5a-5c) were synthesized by reaction of ally isothiocyanate,which was prepared from 3-bromopropene,ammonium thiocyanate,with 2-pyridyl-formic acid(2a),3-pyridylformic acid(3a) and 4-pyridylformic acid(4a),respectively,and then the structures of target products(5a-5c) were characterized by IR,1HNMR and elemental analysis respectively. |
| |
| Keywords: | 1-pyridinoyl-4-allylaminothiourea allylamminothiourea synthesis |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
