| 水相中相转移催化剂和金属促进的高效羰基化合物烯丙基化反应 |
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| 引用本文： | 杨光,查正根,汪志勇. 水相中相转移催化剂和金属促进的高效羰基化合物烯丙基化反应[J]. 中国科学技术大学学报, 2003, 33(3): 375-379 |
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| 作者姓名： | 杨光 查正根 汪志勇 |
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| 作者单位： | 1. 安徽省宿州师范专科学校,234000
2. 中国科学技术大学化学系,安徽合肥,230026 |
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| 基金项目： | TheprojectsupportedbyNNSFC ( 5 0 0 73021)NSFCofAnhuiProvince( 0 10 463 0)andthefundfromBasementofGreenChemistryinUSTC |
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| 摘 要： | 应用四丁基淀化铵(TBAB)、β—环糊精(β—CD)和四氟硼酸盐(MBF4)作为催化剂，在纯水中加入锡或锌能促进羰基化合物的烯丙基化反应顺利地进行，得到相应的高产率烯丙基化产物。
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| 关 键 词： | 相转移催化剂 羰基化合物 烯丙基化反应 锡（锌） 水 |
Efficient Allylation of Carbonyl Compounds Promoted by Phase Transfer Catalyst and Metal (Sn or Zn) in Water |
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| YANG Guang ,ZHA Zheng gen ,WANG Zhi yong. Efficient Allylation of Carbonyl Compounds Promoted by Phase Transfer Catalyst and Metal (Sn or Zn) in Water[J]. Journal of University of Science and Technology of China, 2003, 33(3): 375-379 |
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| Authors: | YANG Guang ZHA Zheng gen WANG Zhi yong |
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| Affiliation: | YANG Guang 1,ZHA Zheng gen 2,WANG Zhi yong 2 |
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| Abstract: | The allylations of a variety of carbonyl compounds were carried out smoothly in the presence of phase transfer catalysts (PTC) when mediated by tin or zinc in distilled water, giving rise to the corresponding homoallylic alcohols in excellent yields. Particularly, for aryl aldehyde, the corresponding allylation products can be obtined quantatively. |
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| Keywords: | phase transfer catalyst carbonyl compounds allylation Sn (Zn) water |
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