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液晶彩色显示用负性蒽醌型二色性染料的合成
引用本文:祁国珍,王金娣,施善定. 液晶彩色显示用负性蒽醌型二色性染料的合成[J]. 华东理工大学学报(自然科学版), 1991, 0(6)
作者姓名:祁国珍  王金娣  施善定
作者单位:华东化工学院专用化学品研究所(祁国珍,王金娣),华东化工学院物理系(施善定)
摘    要:用1-氨基蒽醌、1,4-二氨基蒽醌、1,5-二氨基蒽醌、1,5-二氨基-4,8-二羟基蒽醌与对烷氧基苯甲酰氯反应,合成了17个对-(烷氧基苯甲酰胺基)蒽醌型负性的二色性染料。用1,5-二氯蒽醌、1,4,5,8-四氯蒽醌与正辛胺、正壬胺反应,合成了3个烷氨基蒽醌型负性的二色性染料。其中有14个是新的化合物。同时测定了染料分子在液晶中的有序参数,讨论了负的二色性染料结构的特点。

关 键 词:染料  蒽醌染料  液晶显示  二色性染料  彩色显示

Syntheses of Negative Anthraquinone Type Dichroic Dyes for Liquid Crystal Colour Display
Qi Guozhen,Wang Jindi and Shi Shanding. Syntheses of Negative Anthraquinone Type Dichroic Dyes for Liquid Crystal Colour Display[J]. Journal of East China University of Science and Technology, 1991, 0(6)
Authors:Qi Guozhen  Wang Jindi  Shi Shanding
Affiliation:Qi Guozhen~*,Wang Jindi~* and Shi Shanding~
Abstract:Seventeen negative dichroic dyes of p-alkoxy-benzoylaminoanthraquinone type were prepared with 1 -aminoanthraquinoe, 1, 4-diaminoanthraquinone, 1,5-diaminoanthraquinone, 1,5-diamino-4, 8-dihydroxyanthraquinone and p-Alkoxybenzoylchloride. Three negative dichroic dyes of alkylaminoanthraquinone type were obtained in that 1,5-dichloroanthraquinone, 1,4,5,8-tetrachloroanthraquinone reacted with n-octylamine and n-nonylamine. 14 among them are new compounds. The order parameter (S) of dye molecules in liquid crystal were determined, and the characteristics of negative dichroic dyes structure were discussed.
Keywords:dyes  anthraquinone dyes  liquid crystal displays  dichroic dyes  colour display
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