| 聚苯乙烯负载的奎宁环催化剂的合成及其在Morita-Baylis-Hillman反应中的应用 |
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| 引用本文： | 张敏娟,余芳芳,He Helen Song,施敏,Toy Patrick H. 聚苯乙烯负载的奎宁环催化剂的合成及其在Morita-Baylis-Hillman反应中的应用[J]. 华东理工大学学报(自然科学版), 2009, 35(1) |
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| 作者姓名： | 张敏娟 余芳芳 He Helen Song 施敏 Toy Patrick H |
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| 作者单位： | 1. 华东理工大学化学与分子工程学院,上海,200237
2. 香港大学化学系,香港 |
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| 摘 要： | 通过3-(4-乙烯基苄氧基)-1-氮杂-双环[2,2,2]辛烷和苯乙烯共聚合制备聚(苯乙烯-共-3-(4-乙烯基苄氧基)-1-氮杂-双环[2,2,2]辛烷),并将其作为非均相催化剂应用于分子内和分子间的Morita-Baylis-Hillman及氮杂-Morita-Baylis-Hillman反应中,在所有这些反应中,产物的产率都可达到中等水平。
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| 关 键 词： | 聚苯乙烯 奎宁环 Morita-Baylis-Hillman反应 |
Synthesis of Polystyrene-Supported Quinuclidine and Its Use as Catalyst for Morita-Baylis-Hillman Reactions |
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| ZHANG Min-juan,YU Fang-fang,He Helen Song,Kwong Cathy Kar-Wing,SHI Min,Toy Patrick H. Synthesis of Polystyrene-Supported Quinuclidine and Its Use as Catalyst for Morita-Baylis-Hillman Reactions[J]. Journal of East China University of Science and Technology, 2009, 35(1) |
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| Authors: | ZHANG Min-juan YU Fang-fang He Helen Song Kwong Cathy Kar-Wing SHI Min Toy Patrick H |
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| Affiliation: | 1.School of Chemistry and Molecular Engineering;East China University of Science and Technology;Shanghai 200237;China;2.Department of Chemistry;University of Hong Kong;Hong Kong;China |
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| Abstract: | Poly(styrene-co-3-(4-vinylbenzyloxy)-1-aza-bicyclo()octane) was prepared by the(co-polymerization) of 3-(4-vinylbenzyloxy)-1-azabicyclo()octane and styrene.This supported tertiary(amine was) used as a heterogeneous catalyst in both intra-and intermolecular Morita-Baylis-Hillman and aza-Morita-Baylis-Hillman reactions.The products of all the reactions can achieve middle-level yields. |
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| Keywords: | polystyrene quinuclidine Morita-Baylis-Hillman reaction |
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