紫外接枝丙烯酰胺改善PMMA表面抗静电性能研究 |
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引用本文: | 王晓丽,陈亚芍.紫外接枝丙烯酰胺改善PMMA表面抗静电性能研究[J].新乡学院学报(自然科学版),2010,27(4):55-59. |
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作者姓名: | 王晓丽 陈亚芍 |
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作者单位: | 王晓丽,WANG Xiao-li(河南科技大学,化工与制药学院,河南,洛阳,471003);陈亚芍,CHEN Ya-shao(陕西省大分子科学重点实验室) |
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摘 要: | 尝试用Ar等离子体技术与紫外光照射技术相结合的方法,在无光引发剂的条件下、在PMMA表面接枝丙烯酰胺(AAm),以改善材料表面的抗静电性能。探讨了等离子体预处理时间、放电功率、气体压强、AAm单体浓度和紫外照射时间对材料表面电阻率的影响。通过ATR-FTIR和扫描电子显微镜(SEM)分析,研究了PMMA接枝AAm前后表面性能和表面形貌的变化。抗静电性能测试结果表明,接枝丙烯酰胺可以使PMMA材料的抗静电性能显著增强,表面电阻率下降了3~5个数量级。
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关 键 词: | PMMA 抗静电性 等离子体 |
Surface Modification of PMMA by Grafted AAm for Improvement of Antistatic Property |
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Authors: | WANG Xiao-li CHEN Ya-shao |
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Institution: | 1.School of Chemical Engineering & Pharmaceutics,Henan University of Science and Technology,Luoyang 471003,China;2.Key Laboratory for Macromolecular Science of Shanxi Province,School of Chemistry and Materials Science,Shanxi Normal University,Xi’an 710062,China) |
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Abstract: | Acrylamide(AAm) was grafted onto the surface of PMMA by Ar plasma pretreatment and UV-induced graft polymerization without photo-initiator to enhance antistatic property of PMMA plates.The effect of plasma-treatment time,plasma discharge power,Ar pressure,AAm monomer concentration and UV irradiation time was studied in the experiment.The surface compositions and microstructure of AAm grafted PMMA plates were studied by ATR-FTIR and Scanning Electron Microscopy(SEM).Results of measuring the surface resistivity indicated that the surface resistivity of AAm-grafted PMMA plates decreased significantly by 3~5 orders of magnitude and the antistatic property was improved remarkably. |
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Keywords: | PMMA |
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