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新型二茂铁衍生物的合成及表征
引用本文:高玉梅,王巧娈,郭书玲.新型二茂铁衍生物的合成及表征[J].许昌师专学报,2010(2):106-108.
作者姓名:高玉梅  王巧娈  郭书玲
作者单位:[1]河南工程学院材料与化学工程系,河南郑州450007 [2]郑州中南杰特超硬材料有限公司,河南郑州450056 [3]河南工业大学化学化工学院,河南郑州450052
摘    要:以二茂铁为原料,以无水三氯化铝为催化剂,合成呋喃甲酰基二茂铁、丙酰基二茂铁,并在此基础上合成了新的二茂铁衍生物二茂铁呋喃甲醇、(R)-二茂铁丙胺,其结构经过IR、1H-NMR法进行了确定.

关 键 词:二茂铁  衍生物  合成  表征

Synthesis and Characterization of Novel Ferrocene Derivatives
GAO Yu-mei,WANG Qiao-luan,GUO Shu-ling.Synthesis and Characterization of Novel Ferrocene Derivatives[J].Journal of Xuchang Teachers College(Social Science Edition),2010(2):106-108.
Authors:GAO Yu-mei  WANG Qiao-luan  GUO Shu-ling
Institution:1. Deperment of Materials and Chemical Engineering, Henan Institute of Engineering, Zhengzhou 450007, China ; 2. Zhengzhou ZhongNan Jete Supeabrasives CO Ltd , Zhengzhou 450056, China ; 3. College of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou 450052, China)
Abstract:Furan-methenylferrocene and propionylferrocene are synthesized through acylable reaction of Friedel- Crafts by using anhydrous aluminum chloride as catalyst, and the new ferrocene derivatives (ferrocene furan carbinol and ferrocene propyl amine) are also synthesized. Their structures are characterized by means of IR and 1H-NMR.
Keywords:ferrocene  derivative  synthesis  characteristics
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