| 铜取代的多金属氧酸盐电催化水氧化性能研究 |
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| 引用本文： | 喻莉,梁钦.铜取代的多金属氧酸盐电催化水氧化性能研究[J].信阳师范学院学报(自然科学版),2022(1):122-127. |
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| 作者姓名： | 喻莉 梁钦 |
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| 作者单位： | 1.信阳师范学院化学化工学院;2.信阳师范学院人事处 |
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| 摘 要： | 合成并表征了一个铜取代的多金属氧酸盐:Cu5(OH)4(H2O)2(A-a-SiW9 O33)2]10-(化合物1),并首次将其用于电催化水氧化体系中进行催化产氧.化合物1不仅在pH值为4.2的酸性环境下具有产氧活性,而且展现出优异的稳定性.同时利用循环伏安、恒电压电解、扫描电镜、能量色散X射线谱等考察了化合物1在电...
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| 关 键 词： | 多金属氧酸盐 光催化 水氧化 |
Polyoxometalate Based Copper Clusters as Catalysts for Electrochemical Water Oxidation |
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| Institution: | ,College of Chemistry and Chemical Engineering, Xinyang Normal University,Personnel Division, Xinyang Normal University |
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| Abstract: | A copper containing polyoxometalate(POM) Cu_5(OH)_4(H_2O)_2(A-a-SiW_9O_(33))_2]~(10-)(compound1) was synthesized and characterized. Compound 1 was tested as the first catalyst for O_2 production via electrocatalytic water oxidation. Meanwhile, compound 1 shows oxygen evolution activity and excellent stability in an acidic medium(pH=4.2). Multiple experiments including cyclic voltammetry, bulk water electrolysis, scanning electron microscope and energy-dispersive X-ray spectrometry measurements results confirm that the difference of the catalytic water oxidation activity and catalytic behavior using compound 1 and CuCl_2 is compelling evidence that compound 1 is a true active species in the electrocatalytic system. |
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| Keywords: | polyoxometalates photocatalysis water oxidation |
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