| 隧道效应在硅酮单分子热反应中的应用 |
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| 引用本文： | 郑不仿,傅强.隧道效应在硅酮单分子热反应中的应用[J].东北师大学报(自然科学版),1996(4):59-61. |
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| 作者姓名： | 郑不仿 傅强 |
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| 作者单位： | [1]大连大学化学系 [2]东北师范大学化学系 |
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| 摘 要： | 采用不对称Ｅｃｋａｒｔ势函数来研究硅酮单分子热反应体系的隧道效应，讨论了温度，压力等因素对单分子反应速度常数及相应的活化能的影响，所得结果与甲醛结果做了比较。
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| 关 键 词： | 不对称Eckart势 隧道效应 热反应 硅酮 热解 |
Application of Tunneling Effect to Thermal Unimolecular Reaction of Shilanone |
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| Zheng Xuefang, Zhang Xiaohui, Guo Ming.Application of Tunneling Effect to Thermal Unimolecular Reaction of Shilanone[J].Journal of Northeast Normal University (Natural Science Edition),1996(4):59-61. |
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| Authors: | Zheng Xuefang Zhang Xiaohui Guo Ming |
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| Abstract: | Based on asymmetrical Eckart potential,the tunneling in the unimolecular reaction of silanone is investigated. It has disscussed the effects of temperature and presure on unimolecular rate constant and activated energy.In addition,it has compared those results with the results of formaldehyde. |
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| Keywords: | asymmeerieal eckart poteneial tunneling effect thermal reaction |
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