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负载型固体酸催化合成乙酸乙酯
引用本文:张翠仙,张会琴,涂华民,齐建国. 负载型固体酸催化合成乙酸乙酯[J]. 河北师范大学学报(自然科学版), 2001, 25(2): 208-210
作者姓名:张翠仙  张会琴  涂华民  齐建国
作者单位:1. 河北师范大学化学系,
2. 河北电子工业学校,
基金项目:河北省科委博士基金!资助课题 (995 470 10 D)
摘    要:制备了负载型催化剂TZ-1,利用其催化乙醇和乙醇的酯化反应考察了载体,活性组份等因素的影响,结果表明,在最佳反应条件下,催化率为98.5%,选择性可达100%,催化剂经9次重复使用,活性下降很小。

关 键 词:固体酸 催化剂 酯化反应 乙酸乙酯 载体 活性组份 酯化率

Synthesis of Acetic Ether by Supported-type Solid Acid
ZHANG Cui-xian ,ZHANG Hui-qin ,TU Hua-min ,QI Jian-guo [WTBZ]. Synthesis of Acetic Ether by Supported-type Solid Acid[J]. Journal of Hebei Normal University, 2001, 25(2): 208-210
Authors:ZHANG Cui-xian   ZHANG Hui-qin   TU Hua-min   QI Jian-guo [WTBZ]
Affiliation:ZHANG Cui-xian 1,ZHANG Hui-qin 2,TU Hua-min 1,QI Jian-guo 1 [WT6BZ]
Abstract:The supported-type solid acid catalysts TZ-1 was prepared,and its catalystic properties and influence of carries or active compositions were tested by the esterification of acetic acid with alcohol.The results show that,the catalysts has excellent catalystic acitivity(98.5 %)and selectivity (100 %) for the esterification.At the optimum conditions,after the catalyst was used repeatedly nine times,the catalytic activity decreases hardly.
Keywords:solid acid  catalyst  esterification
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