| 一种salen镍配合物的合成与晶体结构 |
| |
| 引用本文： | 李立军,达世俊,李瀛. 一种salen镍配合物的合成与晶体结构[J]. 兰州大学学报(自然科学版), 2005, 41(2): 46-49 |
| |
| 作者姓名： | 李立军 达世俊 李瀛 |
| |
| 作者单位： | 兰州大学,功能有机分子化学国家重点实验室,甘肃,兰州,730000 |
| |
| 基金项目： | Supported by National Natural Science Foundation of China(20272062) |
| |
| 摘 要： | 合成和表征了一种新的salen镍配合物,并报道了其单晶衍射数据.化合物4:[NiC28H20Cl2N2O2]·CH2Cl2,M=631.00,单斜,P21/c,a=1.1086(2)nm,b=1.7521(4)nm,c=1.4819(3)nm,β=105.06(3)°,Z=4,V=2.779 5(10)nm3,Dc=1.508 g/cm3,R1=0.0531,R2=0.1136.
|
| 关 键 词： | 手性salen 镍(Ⅱ)二聚配合物 弱键作用 nickel ( Ⅱ ) dimer complex |
Synthesis and crystal structure of a salen nickel complex |
| |
| LI Li-jun,DA Shi-jun,LI Ying. Synthesis and crystal structure of a salen nickel complex[J]. Journal of Lanzhou University(Natural Science), 2005, 41(2): 46-49 |
| |
| Authors: | LI Li-jun DA Shi-jun LI Ying |
| |
| Abstract: | A new salen nickel complex was synthesized and characterized along with the single crystal X-ray diffraction analysis. Compound 4: [NiC28H20Cl2N2O2]·CH2Cl2, M=631.00, Monoclinic,P21/c, a= 1.1086(2)nm, b=1.752 1(4)nm, c=1.4819(3)nm, β=105.06(3)°, Z=4, V=2.7795(10)nm3,Dc=1.508 g/cm3, R1=0.0531, R2=0.1136. |
| |
| Keywords: | chiral salen weak bonding |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
