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Ee系统耦合性质初步研究
引用本文:乔芬,邱庆春. Ee系统耦合性质初步研究[J]. 汕头大学学报(自然科学版), 2006, 0(2)
作者姓名:乔芬  邱庆春
作者单位:汕头大学医学院物理教研室,汕头大学医学院物理教研室 广东汕头515041,汕头大学物理系,广东汕头515063,广东汕头515041,汕头大学物理系,广东汕头515063
基金项目:广东省自然科学基金资助项目(No:34613)
摘    要:使用幺正转化方法对Ee系统的绝热势能进行计算,得到势能面的最低槽,对二次耦合项所引起的绝热势能面的变形做初步探讨;利用Mathematica软件对该系统能量和线性耦合强度的函数关系做数学模拟.与求解繁琐的声子态方法相比,该方法不仅减少了计算量,而且更能体现出相关参量的物理含义.

关 键 词:杨泰勒效应  电声耦合  有效哈密顿量  幺正转化

On the Initial Studies to the Linear Coupling Nature of the Ee System
QIAO Fen,,QIU Qing-chun. On the Initial Studies to the Linear Coupling Nature of the Ee System[J]. Journal of Shantou University(Natural Science Edition), 2006, 0(2)
Authors:QIAO Fen    QIU Qing-chun
Affiliation:QIAO Fen1,2,QIU Qing-chun1,2
Abstract:The adiabatic potentials of the Ee system was calculated using unitary transformation method and the lowest trough of adiabatic potential energy surface was obtained.The distortion of the adiabatic potential energy surface caused by the quadratic coupling term was also initially studied;Moreover,the function relation between the energy of system and linear coupling intensity was mathematically simulated using Mathematica software.Comparing with the methods of calculating massive phonons states,this method in this article not only reduced computations quantity,but also was able to manifest physical mechanism of the relevant constants.
Keywords:Jahn-Teller effect  vibronic coupling  effective Hamiltonian  Unitary transformation
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