| 三苄基吗啉荒酸基锡的合成及晶体结构研究 |
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| 引用本文： | 朱德中,张如芬,尹汉东,马春林.三苄基吗啉荒酸基锡的合成及晶体结构研究[J].聊城大学学报(自然科学版),2002,15(2):13-15. |
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| 作者姓名： | 朱德中 张如芬 尹汉东 马春林 |
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| 作者单位： | 聊城大学,化学化工学院,山东,聊城,252059 |
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| 基金项目： | Weacknowledge the Financial Support of the Shandong Province Science Foundation，国家重点实验室基金 |
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| 摘 要： | 以三苄基氯化锡和吗啉荒酸钠为原料,合成了三苄吗啉荒酸基锡.通过X-射线单晶衍射测定了它们的晶体结构.晶体结构为:三斜晶系,空间群P-1,a=0.984 17（16）nm,b=1.081 63（19）nm,c=1.378 8（2）nm,a=72.850（3）°,β=88.895（3）°,γ=64.231（3）°,Z=2,V=1.252 8（4）nm3,Dx=1.469 g/cm3,μ=1.204 mm-1,F（000）=564,R=0.032 8,wR=0.099 5（I≥2σ（I））,对配位中心锡原子而言,属于五配位的扭曲三角双锥结构.
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| 关 键 词： | 三苄基氯化锡 吗啉荒酸钠 晶体结构 |
SYNTHESIS AND CRYSTAL STRUCTURE OF(PhCH2)3SnS2CN(C4H8O) |
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| ZHU De-zhong,ZHANG Ru-fen,YIN Han-dong,MA Chun-lin.SYNTHESIS AND CRYSTAL STRUCTURE OF(PhCH2)3SnS2CN(C4H8O)[J].Journal of Liaocheng University:Natural Science Edition,2002,15(2):13-15. |
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| Authors: | ZHU De-zhong ZHANG Ru-fen YIN Han-dong MA Chun-lin |
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| Abstract: | The (PhCH2)3SnS2CN (C4H8O)was synthesized by the reaction of tribenzyltin chloride with morpholinyldithiocarbamate, its crystal structure was determined by X-ray single crystal diffraction. The crystallographic data are as follows: triclinic, space group P-1, a = 0. 984 17 (16) nm, b = 1.081 63 (19) nm, c =1.3788(2) nm,a＝72.850(3)°,ββ=88.895(3)°,γ=64.231(3)°,Z=2,V=1.2528(4) nm3,Dx=1. 469 g/cm3,μ= 1.204 mm-1, F(000)=564,R = 0.0328, wR = 0.099 5 (I≥2a (I)). The structures comsist of discrete molecules containing five-corrdinate tin atoms in a seriously distorted tigonal bipyramidal configuration. The unit cell comtains two independent molecules that are practically superimposable. |
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| Keywords: | tribenzyltin chloride morpholinyldithiocarbamate crystal structure |
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