| 水热组合方法在合成亚磷酸镓中的应用 |
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| 引用本文： | 杨磊,赵晓雷,张如意,毕文彦,李素萍.水热组合方法在合成亚磷酸镓中的应用[J].吉林大学学报(理学版),2009,47(1):125-129. |
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| 作者姓名： | 杨磊 赵晓雷 张如意 毕文彦 李素萍 |
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| 作者单位： | 河南理工大学 物理化学系, 河南 焦作 454150 |
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| 基金项目： | 河南省杰出青年科学基金 |
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| 摘 要： | 应用水热溶剂热组合合成方法, 在Ga-H3PO3-1,2-dap(1,2-丙二胺)-EG（乙二醇）/H2O体系中合成了3种三维空旷骨架亚磷酸镓化合物以及1种磷酸镓化合物, 对其进行了红外光谱、 元素分析及X射线单晶衍射结构分析, 并讨论了合成因素对晶化的影响.
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| 关 键 词： | 水热组合合成 晶体结构 亚磷酸镓 空旷骨架 |
| 收稿时间： | 2008-03-11 |
Application of Hydrothermal Combinative Technique to Synthesis of Gallium Phosphite |
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| YANG Lei,ZHAO Xiao-lei,ZHANG Ru-yi,BI Wen-yan,LI Su-ping.Application of Hydrothermal Combinative Technique to Synthesis of Gallium Phosphite[J].Journal of Jilin University: Sci Ed,2009,47(1):125-129. |
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| Authors: | YANG Lei ZHAO Xiao-lei ZHANG Ru-yi BI Wen-yan LI Su-ping |
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| Institution: | Department of Physics chemistry, Henan Polytechnic University, Jiaozuo 454150, Henan Province, China |
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| Abstract: | Three gallium(Ⅲ) phosphites and gallium phosphate were
synthesized by hydrothermal/solvothermal combinative technique under autogeneou
s pressure in the system of Ga-H3PO3-1,2-dap-EG/H2O(1,2-dap:
1,2-diaminopropane, EG: ethyl glycol). Their structures were determined by means of singlecrystal X ray diffraction analysis, IR spectroscopy, inductively coupled
plasma(ICP). In our work, we stressed the synthetic factors on the influence of
the crystallization of such materials. |
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| Keywords: | hydrothermal combinative technique crystal structure gallium phosphite open-framework |
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