一种喹啉类Zn2+荧光比率型探针 |
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引用本文: | 陈嘉韵,潘珺仪,陈志,陈梓亮,马立军.一种喹啉类Zn2+荧光比率型探针[J].华南师范大学学报(自然科学版),2017,49(2):56-60. |
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作者姓名: | 陈嘉韵 潘珺仪 陈志 陈梓亮 马立军 |
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作者单位: | 1.1.化环学院 |
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基金项目: | 广东省自然科学基金项目(2015A030313392);广州市珠江科技新星资助项目(2012J2200026) |
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摘 要: | 以8-氨基喹啉为母体,设计并合成一种Zn2+比率型荧光探针,通过核磁、质谱表征其结构,并利用荧光光谱、紫外-可见吸收光谱等研究了探针的识别性能.结果表明,该探针在pH为4.0~9.5条件下均能有效识别Zn2+,尤其在pH 7.4的生理条件下具有最优的识别能力.探针与Zn2+能形成结合比为1:1的稳定络合物且灵敏度高、选择性强、响应迅速,因此该荧光探针具有在生物及环境等领域有效检测Zn2+的潜力.
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关 键 词: | 荧光探针 |
收稿时间: | 2017-01-21 |
A Ratiometric Fluorescent Probe Based on a Quinoline for Zn2+ |
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Institution: | 1.School of Chemistry &Environment,South China Normal University,Guangzhou 510006,China |
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Abstract: | A ratiometric fluorescence probe based on 8-Aminoquinoline for Zn2+ was designed and synthesis. The structure and characterization were researched by 1HNMR, MS, UV-vis absorption spectrum and fluorescence spectrum. The experiment results indicated that the probe showed good recognition for Zn2+ under pH for 4-9.5 conditions, especially in the pH 7.4, the physiological condition. The probe can combine Zn2+ to a stable complex at the ratio of 1:1. The fluorescence probe showed high sensitivity, excellent selectivity and fast fluorescence response toward Zn2+. Therefore, the probe had the potential to recognize Zn2+ in the fields of life and environment. |
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