| 由铅、钛乙醇盐配合物制备纳米PbTiO3粉体 |
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| 引用本文： | 朱传高,褚道葆. 由铅、钛乙醇盐配合物制备纳米PbTiO3粉体[J]. 吉林大学学报(理学版), 2005, 43(4): 507-512 |
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| 作者姓名： | 朱传高 褚道葆 |
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| 作者单位： | 淮南师范学院,化学系,安徽省,淮南,232001;安徽师范大学,有机化学研究所,安徽省,芜湖,241000 |
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| 基金项目： | 安徽省高等学校青年教师科研基金(批准号:2004jq185)和安徽省淮南市科技局计划项目基金(批准号:2004B16). |
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| 摘 要： | 在0.03 mol/L (Bu4N)Br的乙醇溶液中， 电解钛片4 h， 然后电解铅 片2 h， 每隔30 min加入0.1 mL乙酰丙酮， 制得铅、 钛金属醇盐. 采用红外、 拉曼光谱测试结果表明， 纳米PbTiO3前驱体结构中含有acac-（乙酰丙酮基） ， 可以有效克服团聚现象. 经差热-热重分析、 X射线衍射、 电子透射显微镜测试表 明， 凝胶经乙醇洗涤、 真空干燥24 h后粒径为10 nm； 700 ℃煅烧2 h制得纳米PbTiO 3粉体， 粒径在10~15 nm.
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| 关 键 词： | 电化学 铅 钛乙醇盐配合物 溶胶-凝胶 纳米PbTiO3 |
| 文章编号： | 1671-5489(2005)04-0507-06 |
| 收稿时间： | 2004-09-27 |
| 修稿时间： | 2004-09-27 |
Preparation of Nanocrystalline PbTiO3 Powder by Lead and Titanium Eth oxide Complexes |
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| ZHU Chuan-gao,CHU Dao-bao. Preparation of Nanocrystalline PbTiO3 Powder by Lead and Titanium Eth oxide Complexes[J]. Journal of Jilin University: Sci Ed, 2005, 43(4): 507-512 |
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| Authors: | ZHU Chuan-gao CHU Dao-bao |
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| Affiliation: | 1. Department of Chemistry, Huainan Normal College, Huainan 232001, Anhui Province， China; 2. Institute of Organic Chemistry, Anhui Normal University, Wuhu 241000, Anhui Province， China |
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| Abstract: | The precursor (PbTi(OCH_2CH_3)_(6-y)(acac)_y) of nanocrystalline (PbTiO_3) was prepared by the electrochemical dissolution of titanium for 4 h at 50 and then of lead for 2 h at 40 in an ethanol solution of (0.03) mol/L (Bu_4N)Br. IR and Raman spectroscopy were used to investigate the structure of the precursor. The results show that the precursor contained acac group, which could prevent the precursor from gathering. TG-DT, XRD, and TEM were used to investigate the structure of nano-sized PbTiO_3. The xerogel of 10 nm was obtained by drying in vacuum for 24 h. (PbTiO_3) with a narrow size distribution of 10~15 nm was prepared by heating it at 700 for 2 h. |
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| Keywords: | electro-chemical lead and titanium ethoxide complexes sol-gel nanocrystalline PbTiO_3 |
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