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TiO_2纳米管薄膜的制备及其光电性能研究
引用本文:王立新,郑言贞,陶霞,陈建峰. TiO_2纳米管薄膜的制备及其光电性能研究[J]. 北京化工大学学报(自然科学版), 2010, 37(1): 42-45. DOI: 10.3969/j.issn.1671-4628.2010.01.010
作者姓名:王立新  郑言贞  陶霞  陈建峰
作者单位:北京化工大学 纳米材料先进制备技术与应用科学教育部重点实验室, 北京 100029
基金项目:国家“863”计划(2007AA03Z343);;国家自然科学基金(20776014)
摘    要:将水热法制备的TiO2纳米管在600℃下焙烧,用焙烧产物制备染料敏化太阳能电池中的薄膜电极,同时与未焙烧的TiO2纳米管制备的薄膜电极进行光电性能比较。结果表明,600℃焙烧纳米管产物制备的薄膜电极短路电流和开路电压分别达到17.45mA/cm2和0.60V,光电转化效率提高到5.65%,高于未焙烧的TiO2纳米管制备的薄膜电极相应值,且机械性能良好,不易剥落。

关 键 词:TiO_2  形貌  染料敏化太阳能电池  转化效率
收稿时间:2009-03-16

Photoelectric properties of TiO_2 nanotube films
WANG LiXin,ZHENG YanZhen,TAO Xia,CHEN JianFeng. Photoelectric properties of TiO_2 nanotube films[J]. Journal of Beijing University of Chemical Technology, 2010, 37(1): 42-45. DOI: 10.3969/j.issn.1671-4628.2010.01.010
Authors:WANG LiXin  ZHENG YanZhen  TAO Xia  CHEN JianFeng
Affiliation:Key Laboratory for Nanomaterials, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029, China
Abstract:TiO_2 nanotubes were prepared via a hydrothermal reaction, and then sintered at 600 ℃. The resulting product was used to make the working electrode in dye-sensitized solar cells. The photoelectric properties of TiO_2 nanotubes with and without sintering were compared. It was found that TiO_2 films composed of TiO_2 nanotubes sin-tered at 600 ℃ exhibited a light-to-electricity conversion efficiency of 5.65% with a short-circuit current of 17.45 mA/cm~2 and an open-circuit voltage of 0.60 V; these values are much higher than those obtained using the non-sin-tered TiO_2 nanotubes. TiO_2 films composed of TiO_2 nanotubes sintered at 600 ℃ were also observed to possess better mechanical properties and did not flake off easily.
Keywords:titanium dioxide  morphology  solar cell  conversion efficiency  
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