| 两性纤维素接枝共聚物的合成研究 |
| |
| 引用本文： | 张黎明,谭业邦.两性纤维素接枝共聚物的合成研究[J].中山大学学报(自然科学版),1998,37(2):35-39. |
| |
| 作者姓名： | 张黎明 谭业邦 |
| |
| 作者单位： | Institute of Polymer Science，Zhongshan University，Guangzhou 510275; State Key Laboratory of Polymer Materials Engineering，Chengdu 610065 |
| |
| 基金项目： | 广东省自然科学基金,中国科学院纤维素化学开放研究实验室基金 |
| |
| 摘 要： | 采用ＫＭｎＯ４／Ｈ２ＳＯ４氧化还原引发体系，首次将羧甲基纤维素（ＣＭＣ）与二甲基二烯丙基氯化铵（ＤＭＤＡＡＣ）进行接枝聚合，制备了一系列分子中同时含有阴离子羧甲基和阳离子季铵基团的两性纤维素接枝共聚物．研究了ＣＭＣ取代度、ＤＭＤＡＡＣ加量、ＫＭｎＯ４用量和Ｈ２ＳＯ４浓度对接枝共聚的影响，并对其聚合反应机理作了探讨
|
| 关 键 词： | 两性纤维素接枝共聚物，羧甲基纤维素，二甲基二烯丙基氯化铵，接枝聚合 |
Studies on Synthesis of Amphoteric Cellulosic Graft Copolymers |
| |
| Zhang Liming,Tan Yebang,Yin Xiangchun,Li Zhuomei.Studies on Synthesis of Amphoteric Cellulosic Graft Copolymers[J].Acta Scientiarum Naturalium Universitatis Sunyatseni,1998,37(2):35-39. |
| |
| Authors: | Zhang Liming Tan Yebang Yin Xiangchun Li Zhuomei |
| |
| Abstract: | A series of amphoteric cellulosic graft copolymers, containing anionic carboxymethyl and cationic quaternary ammonium groups, were prepared by the graft copolymerization of carboxymethylcellulose(CMC) with dimethyldiallylammonium chloride(DMDAAC) using potassium permanganate/sulphuric acid initiation system under different conditions.Major factors affecting the polymerization reaction,such as the degree of substitution(DS) of CMC, the amount of DMDAAC, acid concentration and the amount of initiator, were studied, and the mechanism for grafting of DMDAAC onto CMC using the KMnO 4/H 2SO 4 redox system was elucidated. |
| |
| Keywords: | amphoteric cellulosic graft copolymers carboxymethylcellulose dimethyldiallylammonium chloride graft copolymerization |
| 本文献已被 CNKI 维普 等数据库收录！ |
