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Synthetic Application of Indium Hydride
Authors:Akio Baba Naoki Hayashi Makoto Yasuda Ikuya Shibata
Institution:Deparment of Applied Chemistry Gaduate School of Engineering Osaka University Deparment of Applied Chemistry Gaduate School of Engineering Research Center for Environmental Preservation Osaka 5 Japan Yamadaoka Suita Osaka 565-0871
Abstract:1 Results Recently much interest was focused on the indium chemistry. Barbier and, Reformatsky types of reactions are main streams of the chemistry. The synthetic application of indium hydride (HInCl2), however, has been just started in contrast to the chemistry of the same 13th group of elements such as aluminum and boron hydrides. At first we generated the hydride by the transmetallation between Bu3SnH and InCl3, and then found it has both considerable stability and reactivity, and the hydride could b...
Keywords:indium hydride  hydroindation  radical  
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