碳酸盐溶液中富水充填材料的腐蚀及劣化机理 |
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引用本文: | 高萌,刘娟红,吴爱祥. 碳酸盐溶液中富水充填材料的腐蚀及劣化机理[J]. 北京科技大学学报, 2015, 0(8): 976-983. DOI: 10.13374/j.issn2095-9389.2015.08.002 |
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作者姓名: | 高萌 刘娟红 吴爱祥 |
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作者单位: | 北京科技大学土木与环境工程学院,北京,100083 |
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基金项目: | 国家自然科学基金资助项目(51374036),“十二五”国家科技支撑计划资助项目(2012BAB08B02) |
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摘 要: | 为了研究碳酸根离子对富水充填材料的影响,通过强度检测、扫描电镜观察、X射线衍射分析和红外光谱测试,分析富水充填材料在碳酸钠溶液中浸泡后的宏观及微观结构变化,并对其腐蚀及劣化机理进行探讨.富水充填材料在质量分数为10%的碳酸钠溶液中浸泡后,抗压强度随浸泡时间延长大幅度降低,浸泡90 d 后抗压强度比标养28 d 抗压强度降低72.5%,浸泡28 d后出现泥化现象. X射线衍射图谱显示,富水充填材料在质量分数为10%的碳酸钠溶液中浸泡后有碳硫硅钙石生成,且随浸泡时间延长碳硫硅钙石的生成量增大.红外光谱结果未发现[ AlO6]存在,证实在碳酸钠溶液中富水充填材料硬化体中钙矾石急剧减少,转变为烂泥状的碳硫硅钙石;碳硫硅钙石作为无胶结力物质,会对富水充填材料硬化体造成严重破坏,表明碳酸盐溶液对富水充填材料具有腐蚀作用.
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关 键 词: | 充填材料 硫铝酸盐 碳酸盐 腐蚀 劣化 |
Corrosion and deterioration mechanism of water-rich filling materials in carbonate solutions |
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Abstract: | In order to research the impact of carbonate ions on water-rich filling materials, strength testing, scanning electron microscopy, X-ray diffraction analysis and IR spectrum testing were used to analyze the macro- and micro-structural change and the corrosion and deterioration mechanism of the materials in sodium carbonate solutions. It is found that the compressive strength of the materials in a sodium carbonate solution whose mass fraction is 10% decreases significantly with increasing soaking time. When the soak age is 90 d, the compressive strength of the materials decreases by 72. 5% compared with standard curing for 28 d. After soaking for 28 d the specimen surface is muddy. XRD patterns show that after soaking in a sodium carbonate solution whose mass fraction is 10%, thaumasite generates in the materials. With increasing soaking time the amount of thaumasite increases. Infrared spectroscopy results show that there does not exist [ AlO6 ] . This confirms that ettringite in the materials soaking in the sodium carbonate solution drastically reduces and transforms into pulpy thaumasite. As non-cemented materials, thaumasite will cause serious damage to the hardening body of the materials. This shows that the carbonate solution has corrosive action on water-rich filling materials. |
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Keywords: | filling materials sulphoaluminates carbonates corrosion deterioration |
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