| 非水溶剂中难溶盐溶度积的理论计算 |
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| 引用本文： | 王风云,叶静娴,邵文英. 非水溶剂中难溶盐溶度积的理论计算[J]. 南京理工大学学报(自然科学版), 1991, 0(4) |
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| 作者姓名： | 王风云 叶静娴 邵文英 |
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| 作者单位： | 化工学院(王风云，叶静娴)，化工学院(邵文英) |
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| 摘 要： | 该文根据以静电作用、取向作用、诱导作用和色散作用为基础的分子间相互作用力,对AgCl、AgBr、AgI、AgN_3、AgSCN及AgAc等6种难溶盐在MeOH、EtOH、MeCN、DMF、DMAC、DMSO和HCONH_2等7种非水溶剂中的离解平衡常数K_(SP)进行了理论计算,计算结果与文献值吻合较好。
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| 关 键 词： | 非水溶液 溶度积 相互作用力 |
A CalCulation of Solubiity Products in Nonaqueous Solvents |
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| Wang Fengyun Chemical Engineering School et al. A CalCulation of Solubiity Products in Nonaqueous Solvents[J]. Journal of Nanjing University of Science and Technology(Nature Science), 1991, 0(4) |
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| Authors: | Wang Fengyun Chemical Engineering School et al |
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| Affiliation: | Wang Fengyun Chemical Engineering School et al |
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| Abstract: | This article is a theoretical calculation of activity product ofseveral silver salts in a number of nonaqueous solvents. According to the in-teraction force theory which based on the interaction energy of electrostatic,orientation, induction & dispersion. The accordance between the calculatedvalues of pK_(SP) and those from literatures is good. |
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| Keywords: | non-aqueous solution solubility product interactions |
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