| 富勒醇的合成及其光谱特性 |
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| 引用本文： | 高飞,;张燕辉,;王亚梅,;詹峰萍,;邱玮玮.富勒醇的合成及其光谱特性[J].漳州师院学报,2008(4):82-84. |
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| 作者姓名： | 高飞 ;张燕辉 ;王亚梅 ;詹峰萍 ;邱玮玮 |
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| 作者单位： | [1]漳州师范学院化学与环境科学系,福建漳州363000 |
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| 基金项目： | 福建省自然科学基金计划资助项目（2006J0269（U0650025））;福建省青年科技人才创新项目（2004J051）;漳州师范学院科研启动基金（L20476） |
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| 摘 要： | 以C60为原料，选用三种方法制备了富勒烯多羟基衍生物——富勒醇，发现四丁基氢氧化铵（TBAH）催化碱法的产率最高，所制备的产物在水中的溶解度最大（15．3mg／mL）．同时，考察了产物的红外、紫外可见、荧光和磷光光谱的特性．
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| 关 键 词： | 水溶性富勒烯 富勒醇 合成 光谱特性 |
Synthesis and Spectral Characteristics of Fullerenols |
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| Institution: | GAO Fei, ZHANG Yan-hui, WANG Ya-mei, ZHAN Feng-ping, QIU Wei-wei (Department of Chemistry and Environmental Science, Zhangzhou Normal University, Zhangzhou, Fujian 363000, China) |
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| Abstract: | Water-soluble polyhydroxyl-fullerenes （fullerenols） were prepared by three methods. The experimental results showed that, the product yield was the highest and the solubility of product in water was greatest （15.3 mg / mL） by the reaction of C60 with NaOH using tetrabutylammonium hydroxide （TBAH） as a phase transfer catalyst. At the same time, the products were characterized by IR, UV-Vis, fluorescence and phosphorescence spectrometry. |
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| Keywords: | water-soluble fullerene fullerenols systhesis spectral characteristics |
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