| 聚甲基丙烯酸薄荷醇酯手性高分子的控制合成及表征 |
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| 引用本文： | 沈俏艳,徐永平,李文清,胡自强,来国桥.聚甲基丙烯酸薄荷醇酯手性高分子的控制合成及表征[J].杭州师范大学学报(自然科学版),2011(3):248-252. |
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| 作者姓名： | 沈俏艳 徐永平 李文清 胡自强 来国桥 |
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| 作者单位： | 杭州师范大学有机硅化学及材料技术教育部重点实验室;杭州师范大学材料与化学化工学院; |
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| 基金项目： | 国家863计划项目(2006AA03A134); 杭州市科技发展计划项目(20100331T11) |
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| 摘 要： | 利用甲基丙烯酰氯与L-薄荷醇反应合成了甲基丙烯酸薄荷醇酯手性单体,单体通过原子转移自由基聚合(atom transfer radical polymerization,ATRP)的方法控制合成了聚甲基丙烯酸薄荷醇酯手性高分子,并对所合成聚合物的结构进行了1H NMR,13C NMR,CD和GPC的表征.结果表明,所得到...
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| 关 键 词： | L-薄荷醇 甲基丙烯酸-L-薄荷醇酯 原子转移自由基聚合(ATRP) 手性聚合物 |
The Controllable Synthesis and Representation of Menthyl Methacrylate |
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| Authors: | SHEN Qiao-yan XU Yong-ping LI Wen-qing HU Zi-qiang LAI Guo-qiao |
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| Institution: | SHEN Qiao-yan,XU Yong-ping,LI Wen-qing,HU Zi-qiang,LAI Guo-qiao(1.Key Laboratory of Organosilicon Chemistry and Material Technology of Education Ministry,Hangzhou Normal University,Hangzhou 310012,China,2.College of Material,Chemistry and Chemical Engineering,Hangzhou 310036,China) |
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| Abstract: | The experiment synthesized the L-menthyl methacrylate by the reaction of methacryloyl chloride and L-menthol,synthesized the chiral polymers by atom transfer radical polymerization,and represented the chiral polymers by 1H NMR,13C NMR,Circular Dichroism(CD) as well as gel permeation chromatography(GPC).The result show that the chiral polymers obtained are high polymers which have narrow molecular weight distribution and optical activity. |
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| Keywords: | L-menthol L-menthyl methacrylate atom transfer radical polymerization(ATRP) chiral polymer |
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