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粘度法确定高分子混溶性的叛据及其关系
引用本文:钱家盛,毕红,章于川,朱平平,杨海洋.粘度法确定高分子混溶性的叛据及其关系[J].合肥工业大学学报(自然科学版),2001,24(2):251-255.
作者姓名:钱家盛  毕红  章于川  朱平平  杨海洋
作者单位:1. 安徽大学化学系,
2. 中国科学技术大学高分子科学与工程系,
摘    要:对用稀溶液粘度法确定不同高分子之间混溶性的Δb判据、a判据和Δη]判据进行了深入的研究,发现三者虽然形式上有所不同,但是都从不同的侧面反映了不同高分子之间相互作用参数k

关 键 词:相互作用  混溶性  粘度测定  聚甲基丙烯酸甲酯(PMMA)  聚醋酸乙烯酯(PVAc)
文章编号:1003-5060(2001)02-0251-05
修稿时间:2000年10月31

On the correlation between three criteria available to the determination of polymer-polymer compatibility by viscosity measurement
QIAN Jia-sheng,Bi Hong,ZHANG Yu-Chuan,ZHU Ping-ping,YANG Hai-yang.On the correlation between three criteria available to the determination of polymer-polymer compatibility by viscosity measurement[J].Journal of Hefei University of Technology(Natural Science),2001,24(2):251-255.
Authors:QIAN Jia-sheng  Bi Hong  ZHANG Yu-Chuan  ZHU Ping-ping  YANG Hai-yang
Abstract:Investigation on the criteria Δb, α and Δη] available to the determination of polymer-polymer compatibility by viscosity measurement indicates that, though not the same in form, these criteria chiefly depend upon the Huggins mutual interaction parameter kAB. The influence of absolute value of kAB upon polymer-polymer compatibility can be indicated by Δη] criterion, whereas the influence of relative value of kAB upon polymer-polymer compatibility can be indicated by Δb and α criteria. Both Δb criterion and Δη] criterion were employed in this article to study the compatibility between poly (methyl methacrylate) (PMMA) and poly(vinyl acetate) (PVAc).
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