| 含硫的N-甲氧基氨基甲酸甲酯的合成及生物活性 |
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| 引用本文： | 李仲英,李世林,刘卫东,兰世林.含硫的N-甲氧基氨基甲酸甲酯的合成及生物活性[J].湖南大学学报(自然科学版),2006,33(6):103-105. |
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| 作者姓名： | 李仲英 李世林 刘卫东 兰世林 |
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| 作者单位： | 湖南大学,化学化工学院,湖南,长沙,410082;国家农药创制工程技术研究中心,湖南,长沙,410007;湖南师范大学,化学化工学院,湖南,长沙,410081 |
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| 基金项目： | 国家“十五”科技攻关项目(2004BA308A22)，湖南省杰出青年科学基金资助项目(04JJ1009) |
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| 摘 要： | 为了寻找高效、低毒的新农药,采用活性结构拼接法合成了7个具有新型结构的N-甲氧基-N-2-(甲硫基亚甲基-取代苯亚胺-硫亚甲基)苯基]氨基甲酸甲酯化合物.其结构经1H NMR,IR,LC/MS进行了表征.生物活性测定表明:5b,5g在50 mg/L下对稻瘟病(Pyricularia oryzae)的抑菌活性达90%.
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| 关 键 词： | 合成 N-甲氧基-N-苯基氨基甲酸酯 亚胺 杀菌活性 |
| 文章编号： | 1000-2472（2006）06-0103-03 |
| 收稿时间： | 02 1 2006 12:00AM |
| 修稿时间： | 2006-02-01 |
Synthesis and Fungicidal Activity of Methyl N-Methoxylcarbamates Containing Sulfur |
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| LI Zhong-ying,LI Shi-lin,LIU Wei-dong,LAN Shi-lin.Synthesis and Fungicidal Activity of Methyl N-Methoxylcarbamates Containing Sulfur[J].Journal of Hunan University(Naturnal Science),2006,33(6):103-105. |
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| Authors: | LI Zhong-ying LI Shi-lin LIU Wei-dong LAN Shi-lin |
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| Institution: | 1. College of Chemistry and Chemical Engineering, Hunan Univ, Changsha, Hunan 410082, China; 2. National Engineering Reseaeh Center for Agrochemicals, Changsha, Hunan 410007,China; 3.College of Chemistry and Chemical Engineering, Hunan Normal Univ,Changsha,Hunan 410081 ,China |
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| Abstract: | In order to find new pesticides with higher effectiveness and lower toxicity,seven methyl N-methoxy-N-{2-methylthiomethano(substituted-phenylimino)thiomethylene]phenyl}-carbamates were synthesized according to the substructure link principle.All compounds were confirmed by()~1H NMR,IR and LC/MS.The results of preliminary fungicidal tests showed that the inhibitory ratio of 5b and 5g against Pyricularia oryzae were 90.9% at the concentration of 50 mg/L. |
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| Keywords: | synthesis N-methoxy-N-phenylcarbamates imine fungicidal activity |
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