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低密度聚乙烯结晶与熔化行为研究
引用本文:吕亚非.低密度聚乙烯结晶与熔化行为研究[J].北京化工大学学报(自然科学版),1989(2).
作者姓名:吕亚非
作者单位:北京化工学院高分子材料研究所
摘    要:作者用DSC法研究了LDPE的等温和非等温结晶动力学和熔化行为。LDPE的平衡熔点和晶片折迭表面自由能分别为111.7℃和1.33×10~(-11)J/m~2,有8%的长支链参与主链结晶。

关 键 词:低密度聚乙烯  结晶动力学  熔化行为

Crystallization and Melting Behavior of Low-Density Polyethylene
Lu Yafei.Crystallization and Melting Behavior of Low-Density Polyethylene[J].Journal of Beijing University of Chemical Technology,1989(2).
Authors:Lu Yafei
Institution:Institute of Polymer Materials
Abstract:The isothermal and n on isothermal crystallization kinetics and melting behavior of low-density polyethylene (LDPE)were studied by using DSC, It is shown that the crystallization of about 8 % longer branching chain of LDPE could be observed under nonisothermal conditions. The equilibrium melting temperature and interfacial free energy per sequence as it energes from the basal plane of the nueler of LDPE were determined under isothermal conditions,
Keywords:low-density polyethylene  crystallization kinetics  melting behavior    
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