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Co-Cu-Mg-Al四元类水滑石的合成与表征
引用本文:刘炳华.Co-Cu-Mg-Al四元类水滑石的合成与表征[J].淮阴师范学院学报(自然科学版),2006,5(3):216-218,232.
作者姓名:刘炳华
作者单位:淮阴师范学院,化学系,江苏,淮安,223300;南京大学,化学系,江苏,南京,210093
摘    要:以共沉淀法合成了1.5Co/0.5Cu/Al,1.25Co/0.25Cu/0.5Mg/Al,Co/0.5Cu/0.5Mg/Al和Co/Cu/Al等样品,采用TG-DSC和XRD进行了表征.结果表明,1.5Co/0.5Cu/Al,1.25Co/0.25Cu/0.5Mg/Al和Co/0.5Cu/0.5Mg/Al样品都形成类水滑石(HTLcs),而Co/Cu/Al样品因Jahn-Teller效应未能形成HTLcs.

关 键 词:CoCuMgAl类水滑石  XRD  TG-DSC
文章编号:1671-6876(2006)03-0216-03
收稿时间:2006-06-06
修稿时间:2006年6月6日

Synthesis and Characterization of CoCuMgAl Hydrotalcite-like Compounds
LIU Bing-hua.Synthesis and Characterization of CoCuMgAl Hydrotalcite-like Compounds[J].Journal of Huaiyin Teachers College(Natrual Science Edition),2006,5(3):216-218,232.
Authors:LIU Bing-hua
Abstract:The samples of 1.5Co/0.5Cu/Al,1.25Co/0.25Cu/0.5Mg/Al,Co/0.5Cu/0.5Mg/Al and Co/Cu/Al were prepared by using coprecipitation method.The measured methods of XRD and TG-DSC were used to study these samples.The results indicated that 1.5Co/0.5Cu/Al,1.25Co/0.25Cu/0.5Mg/Al and Co/0.5Cu/0.5Mg/Al could form hydrotalcite-like compounds(HTLcs) while the Co/Cu/Al could not form the structure of HTLcs,likely due to the Jahn-Teller effect.
Keywords:CoCuMgAl HTLcs  XRD  TG-DSC
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