双光子活性配合物的研究进展

论文根据笔者课题组的近期工作,对双光子活性配合物的设计合成及其在生物学中的应用的探索,按照不同金属分类进行了综述.以其生物学应用为导向,利用配合物的结构特点,有机配体的可设计性强,金属离子的选择性广,设计合成了一系列双光子活性高、生物相容性好的配合物.实验结合理论系统地研究了配合物结构-性质相关性,探索了配合物光功能材料在生物学方面的应用.对配合物材料在生物学方面的应用进行了展望.

A survey of two photon absorption metal-complexes

In this paper, the two photon absorption (TPA) complexes with exploration of biological applications are reviewed based on the authors' recent work.A series of TPA complexes oriented by biological applications with biocompatibility were designed and synthesized, which possess both advantages of easy tailored organic ligands and selectivity of metal ion centers.The structure-property relationships were systematically studied both experimentally and theoretically.The TPA functional materials in the biological application were explored.Finally, the development status of TPA complexes is summarized, and the application prospect of these materials in biology is proposed.