| 导电聚吡咯电极的现场红外光谱 |
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| 引用本文： | 谢虹,严曼明.导电聚吡咯电极的现场红外光谱[J].复旦学报(自然科学版),1997,36(1):15-20. |
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| 作者姓名： | 谢虹 严曼明 |
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| 作者单位： | 复旦大学化学系!上海，200433 |
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| 摘 要： | 利用循环伏安法，现场红外反射光谱法研究了电聚合的聚吡咯膜电极在电化学氧化还原过程中性质和结构的变化。结果表明，聚吡咯膜电极在电化学氧化还原过程中呈现薄层电极的特点，聚吡咯中每１２个吡咯单元中有１个单元参加反应。
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| 关 键 词： | 聚吡咯 红外光谱 电极 电化学 氧化 还原 |
In situ FTIR spectroscopic study of conducting polypyrrole electrode |
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| Xie Hong, Yan Manming, Jiang Zhiyu.In situ FTIR spectroscopic study of conducting polypyrrole electrode[J].Journal of Fudan University(Natural Science),1997,36(1):15-20. |
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| Authors: | Xie Hong Yan Manming Jiang Zhiyu |
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| Institution: | Department of Chemistry |
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| Abstract: | The character and structure changes of polypyrrole (PPy) in the process of electrochemical oxidation-reduction was studied using cyclic voltammetry and in situ FTIR spectroscopy. The result shows that the polymerized PPy film electrode is of thin layer electrode model in the process of electrochemical oxidation-reduction. One of every 12 pyrrole units in the polypyrrole is involved in the reaction. It was found that the IR absorption of C=C,C-N and N-H bonds in PPy structure increased as the electropotential jumped positively. The molecular structure may trun towards quinoid mode. |
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| Keywords: | polypyrrole in situ FTIR spectra |
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