| 基于含咪唑衍生物的逻辑门可控体系的研究 |
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| 引用本文： | 张创,许祖勋,薛龙.基于含咪唑衍生物的逻辑门可控体系的研究[J].湖北大学学报(自然科学版),2013(4):431-436. |
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| 作者姓名： | 张创 许祖勋 薛龙 |
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| 作者单位： | [1]湖北大学材料科学与工程学院,湖北武汉430062 [2]功能材料绿色制备与应用教育部重点实验室（湖北大学）,湖北武汉430062 |
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| 基金项目： | 湖北省自然科学基金（2011CDA005）资助 |
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| 摘 要： | 设计基于化合物1-（2-（4-（4-（4，5-二苯基-1H-咪唑-2-）苯基）哌嗪-1-乙氧基）乙基）-4-（4，5-二苯基-1H-咪唑-2-苯基）哌嗪（EDIPP）上的多信号交流的分子开关，化合物EDIPP对酸、金属离子敏感，特别对锌离子有特殊的选择性．该化合物的荧光强度和发射波长也能随酸、金属离子的调节而发生相应变化．在此基础上，实现2个输出信号响应2个输入信号的复杂分子开关．
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| 关 键 词： | EDIPP 逻辑门可控体系 分子开关 |
Logic gate controllable system based on imidazole derivatives |
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| ZHANG Chuang,XU Zuxun,XUE Long.Logic gate controllable system based on imidazole derivatives[J].Journal of Hubei University(Natural Science Edition),2013(4):431-436. |
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| Authors: | ZHANG Chuang XU Zuxun XUE Long |
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| Institution: | 1. School of Materials Science and Engineering, Hubei University,Wuhan 430062 ,China 2. Key Laboratory of Green Preparation and Application for Materials(Hubei University), Ministry of Education,Wuhan 430062,China) |
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| Abstract: | Multi-signal molecular switch based on 1-（2-（4-（4-（4, 5-diphenyl-lH-imidazole-2-）- phenyl） piperazine-l-ethoxy） ethyl）-4-（ 4, 5-diphenyl-1H-imidazole-2-phenyl） piperazine （EDIPP） was designed in this paper. EDIPP exhibited sensitivity to acid and metal ions, especially had special selectivity to Zinc ions, and its fluorescence intensity and emission wavelength changed in pace with acid and metal ions adjustments. On this basis, complex molecular switch with two output signals responding for two input signals was achieved. |
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| Keywords: | EDIPP logic gate controllable system molecular switch |
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