| C_（60）-吡咯烷衍生物的合成及表征 |
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| 引用本文： | 史娟兰,陈建平,郑梅霞,汪庆祥,高飞.C_（60）-吡咯烷衍生物的合成及表征[J].漳州师院学报,2011(2):58-61. |
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| 作者姓名： | 史娟兰 陈建平 郑梅霞 汪庆祥 高飞 |
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| 作者单位： | 漳州师范学院化学与环境科学系,福建漳州363000 |
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| 基金项目： | 福建省自然科学基金计划资助项目（2006J0269（U0650025））; 福建省青年科技人才创新项目（2004J051）; 漳州师范学院科研启动基金（L20476）; 福建省研究生教育创新基地资助项目 |
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| 摘 要： | 以苏氨酸、对苯二甲醛及C60为原料,在氮气保护下,恒温（90℃）反应24 h,经硅胶柱色谱分离纯化,得到目标产物.利用红外光谱、1H核磁共振谱以及质谱等测试手段对产物进行表征,初步推断该产物为富勒烯吡咯烷衍生物,其分子式为C60（C11NH13O2）,并用紫外-可见吸收光谱、荧光光谱及微分脉冲伏安法测定了该物质的光学及电化学性质.
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| 关 键 词： | 苏氨酸 对苯二甲醛 C60 合成 表征 |
Synthesis and Characterization of Fulleropyrrolidine Derivative |
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| SHI Juan-lan,CHEN Jian-ping,ZHENG Mei-xia,WANG Qing-xiang,GAO Fei.Synthesis and Characterization of Fulleropyrrolidine Derivative[J].Journal of ZhangZhou Teachers College(Philosophy & Social Sciences),2011(2):58-61. |
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| Authors: | SHI Juan-lan CHEN Jian-ping ZHENG Mei-xia WANG Qing-xiang GAO Fei |
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| Institution: | (Department of Chemistry and Environmental Science,Zhangzhou Normal University,Zhangzhou Fujian 363000,China) |
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| Abstract: | A new compound was synthesized by the reaction of C60 with threonine and terephthalaldehyde in refluxing toluene under a nitrogen atmosphere for 24 h.The crude reaction mixture was purified by column chromatography on a silica gel to give a product.The product was characterized by FT-IR,1HNMR and MS,and could therefore be presumed as fulleropyrrolidine derivative（C60（C11NH13O2））.The optical and electrochemical properties of the derivative were determined by UV-Vis,FL and differential pulse voltammetry. |
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| Keywords: | Threonine Terephthalaldehyde C60 Synthesis Characterization |
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