| Self-assembly of N-3-γ-pyridyl Aza[60]fulleroid on Au(111) |
| |
| 引用本文： | ZHOUYunshen WANGKedong ZHAOFengzhou WANGBing HOUJianguo WANGShu LIYuliang. Self-assembly of N-3-γ-pyridyl Aza[60]fulleroid on Au(111)[J]. 科学通报(英文版), 2005, 50(5): 406-411 |
| |
| 作者姓名： | ZHOUYunshen WANGKedong ZHAOFengzhou WANGBing HOUJianguo WANGShu LIYuliang |
| |
| 作者单位： | [1]HefeiNationalLaboratoryforPhysicalSciencesatMicroscale,StructureResearchLab,UniversityofScienceandTechnologyofChina,Hefei230026,China [2]KeyLaboratoryofOrganicSolids,InstituteofChemistry.ChineseAcademyofSciences,Beijing100080,China |
| |
| 摘 要： | Self-assembled monolayers of novel C60 derivative, N-3-γ-pyridyl Aza[60]fulleroid (C60Py), on Au(111) were studied by a scanning tunneling microscope under ultrahigh vacuum (UHV). C60Py molecules were assembled on Au (111) via pyridyl nitrogen-Au interaction. The sole assembly of C60PY molecules on Au (III) only exhibited randoml aggregation of C60PY even the films were annealed at 50 and 105℃ .By co-assembling with benzyl mercaptan (BM), the C60PyBM films showed highly dense aggregation, but C60Py assemblies still had disordered structure. After the co-assembled C60Py-BM films were annealed at 50℃, BM molecules were partially desorbed, but the assembly of C60Py remained without obvious change. After the co-assembled C60Py-BM films were further annealed at 105℃, the C6oPy monolayers with ordered structure were obtained, while the BM molecules were nearly thoroughly desorbed from the surface. Here, the BM molecules play a key role as a surfactant in the formation of the ordered C6oPy monolayer.
|
| 关 键 词： | 自组合特征 N-3-γ-氮杂吡啶[60] 金 碳60 化学特征 表面活性剂 |
| 收稿时间： | 2005-01-20 |
Self-assembly of N-3-γ-pyridyl Aza[60]fulleroid on Au(111) |
| |
| ZHOU Yunshen,WANG Kedong,ZHAO Fengzhou,WANG Bing,HOU Jianguo,WANG Shu , LI Yuliang Hefei National Laboratory for Physical Sciences at Microscale,Structure Research Lab,University of Science and Technology of China,Hefei ,China, Key Laboratory of Organic Solids. Self-assembly of N-3-γ-pyridyl Aza[60]fulleroid on Au(111)[J]. Chinese science bulletin, 2005, 50(5): 406-411 |
| |
| Authors: | ZHOU Yunshen WANG Kedong ZHAO Fengzhou WANG Bing HOU Jianguo WANG Shu & LI Yuliang Hefei National Laboratory for Physical Sciences at Microscale Structure Research Lab University of Science Technology of China Hefei China Key Laboratory of Organic Solids |
| |
| Affiliation: | ZHOU Yunshen, WANG Kedong, ZHAO Fengzhou, WANG Bing, HOU Jianguo, WANG Shu & LI Yuliang Hefei National Laboratory for Physical Sciences at Microscale, Structure Research Lab, University of Science and Technology of China, Hefei 230026, China; Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China |
| |
| Abstract: | Self-assembled monolayers of novel C60 derivative, N-3-γ-pyridyl Aza[60]fulleroid (C60Py), on Au(111) were studied by a scanning tunneling microscope under ultrahigh vacuum (UHV). C60Py molecules were assembled on Au (111) via pyridyl nitrogen-Au interaction. The sole assembly of C60Py molecules on Au (111) only exhibited randoml aggre-gation of C60Py even the films were annealed at 50 and 105℃. By co-assembling with benzyl mercaptan (BM), the C60Py- BM films showed highly dense aggregation, but C60Py as-semblies still had disordered structure. After the co-assembled C60Py-BM films were annealed at 50℃, BM molecules were partially desorbed, but the assembly of C60Py remained without obvious change. After the co-assembled C60Py-BM films were further annealed at 105℃, the C60Py monolayers with ordered structure were obtained, while the BM molecules were nearly thoroughly desorbed from the surface. Here, the BM molecules play a key role as a surfac-tant in the formation of the ordered C60Py monolayer. |
| |
| Keywords: | N-3-γ-pyridyl Aza[60]fulleroid (C60Py) scanning tunneling microscopy self-assembled monolayers (SAMs) surfactant co-assembly. |
| 本文献已被 CNKI 维普 等数据库收录！ |
| 点击此处可从《科学通报(英文版)》浏览原始摘要信息 |
|
点击此处可从《科学通报(英文版)》下载全文 |
|
