梯形有机锡配合物的设计、合成及晶体结构研究 |
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引用本文: | 王珍,;孙君善. 梯形有机锡配合物的设计、合成及晶体结构研究[J]. 泰山学院学报, 2014, 0(6): 93-96 |
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作者姓名: | 王珍, 孙君善 |
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作者单位: | [1]临清第一中学,山东临清252600; [2]泰山学院国有资产处,山东泰安271021 |
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摘 要: | 本文合成了新的配体5-((4-氟苄基)氨基)-2,3,4噻二唑-2-硫酮(L1)与二烃基锡化合物,并对它们进行了系统研究,得到了一种梯形的有机锡水解产物.从晶体结构上看,这些有机锡衍生物中含有两种锡原子的配位环境,配体发生了构型转换,配体杂环上的氮原子与锡发生了配位作用.
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关 键 词: | 有机锡 梯形 晶体结构 |
Research on Design,Synthesis and Crystal structure of Ladder-type Organotin Complex |
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Affiliation: | WANG Zhen, SUN Jun -shan ( 1. Linqing No. 1 Middle School, Linqing,252600 ; 2. Division of State Owned Assets Management, Taishan University ,Tai'an ,271000, China) |
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Abstract: | In this section, we synthesize a new ligand: 5 - ( (4 -fluorobenzyl) amino) -2, 3 - thiadi- azole -2 -thione (L1) and diorganotin compounds and study this organotin complex systematically. We have obtained a ladder- type organotin complex. The Sn atoms in crystal structure contains two coordinating envi- ronment and the configuration of the ligand occurs conversion. The ligand coordinates to Sn atom by N atom from the heterocyclic ring. |
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Keywords: | organotin ladder crystal structure |
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