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| 一维配位聚合物[Ni{S_2P(OCH_2CH_2Ph)_2}_2(4,4'-bipy)]_n的合成与晶体结构 | |
| 引用本文： | 李玉龙,邹立科,林肖,张秀兰,朱莎莎.一维配位聚合物[Ni{S_2P(OCH_2CH_2Ph)_2}_2(4,4'-bipy)]_n的合成与晶体结构[J].四川理工学院学报(自然科学版),2013,26(2):20-24. |
| 作者姓名： | 李玉龙 邹立科 林肖 张秀兰 朱莎莎 |
| 作者单位： | 1. 四川理工学院功能材料研究所,四川自贡643000;四川理工学院化学与制药工程学院,四川自贡643000 2. 四川理工学院功能材料研究所,四川自贡,643000 3. 四川理工学院化学与制药工程学院,四川自贡,643000 |
| 基金项目： | 四川省科技厅项目，四川理工学院引进人才项目 |
| 摘 要： | 在丙酮溶剂中,双((O,O’-二苯乙基)二硫代磷酸)合镍配合物与双齿桥联氮碱配体4,4’-联吡啶(4,4’-bipy)反应,得到了一维配位聚合物Ni{S2P(OCH2CH2Ph)2}2(4,4’-bipy)]n,用元素分析、红外光谱、1H NMR、13C NMR、31P NMR和X-射线衍射技术对其结构进行了表征。该化合物属单斜晶系,C 2/c空间群,晶胞参数为a=29.500(4),b=11.289(3),c=13.407(4),β=99.44(4)°,V=4404.4(18)3,Z=4,C42H44N2NiO4P2S4,Mr=889.68,Dc=1.342 g/cm3,F(000)=1856,μ(MoKα)=0.744 mm-1。可观测衍射点为2550个,R=0.052,wR=0.1329(I>2σ(I)),所有数据的R=0.0971,wR=0.1489。 |
| 关 键 词： | O O’-二苯乙基二硫代磷酸 配位聚合物 晶体结构 |
Synthesis and Crystal Structure of 1 D Chain Coordination Polymer [Ni{ S2 P (OCH2 CH2 Ph)2}2 (4, 4'-bipy)]n |
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| LI Yu-long , ZOU Li-ke , LIN Xiao , ZHANG Xiu-lan , ZHU Sha-sha.Synthesis and Crystal Structure of 1 D Chain Coordination Polymer [Ni{ S2 P (OCH2 CH2 Ph)2}2 (4, 4'-bipy)]n[J].Journal of Sichuan University of Science & Engineering:Natural Science Editton,2013,26(2):20-24. | |
| Authors: | LI Yu-long ZOU Li-ke LIN Xiao ZHANG Xiu-lan ZHU Sha-sha |
| Institution: | a(a.Institute of Functional Materials;b.School of Chemical and Pharmacentical Engineering,Sichuan University of Science & Engineering,Zigong 643000,China) |
| Abstract: | A ternary coordination polymerNi{S2P(OCH2CH2Ph)2}2(4,4'-bipy)] is synthesized by treatment of BisO,O'-di(2-phenylethyl)dithiophosphato] Nickel(II)complexNi{S2P(OCH2CH2Ph)2}2] with 4,4'-Bipyridine in acetone and fully characterized by elemental analysis and IR,1H NMR,13C NMR,31P NMR spectroscopies.In addition,the molecular structure of the complex is established by X-ray crystallography.The crystal of coordination polymer crystallizes in monoclinic,spacegroup C 2/cwith a=29.500(4),b=11.289(3),c=13.407(4),β=99.44(4)°,V=4404.4(18)3,Z=4,C42H44N2NiO4P2S4,Mr=889.68,Dc=1.342 g/cm3,F(000)=1856 and μ(MoKα)=0.744 mm-1.The results are that the final R=0.0520 and wR =0.1329 for 2550 observed reflections with I > 2σ(I) and R=0.0971 and wR=0.1498 for all data. |
| Keywords: | O O'-di(2-phenylethyl)dithiophosphato coordination polymer crystal structure |
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