纳米WS_2润滑晶体的制备与量子尺寸效应

纳米WS2 润滑晶体是一种性能优良的新型固体润滑材料 .作者介绍了一种用机械 物理固相反应装置制备纳米WS2 润滑晶体的新方法 ;用XRD对WS2 纳米晶体进行了物相分析 ;用ESCALAB MKⅡ型电子能谱仪分析了不同粒径的试样W 4f7/2 ,S 2p3/2 电子结合能的变化 ,并对 5 0nm和 10mm粒径的S W S纳米簇团的S 2p3/2 电子能谱结构进行谱图拟合 .分析结果表明 :XRD图样显示为WS2 相单相 ;在S W S纳米簇团中存在显著的量子尺寸效应 ,该效应强化了硫原子电子壳层间的轨道杂化 ,使纳米级的WS2 润滑晶体形成了 1个没有悬键的、化学性能稳定的中空球体 ,在润滑过程中 ,这种结构可使体系保持较强的化学稳定性 ,能耗降低 .

Preparation and quantum size effect of nano WS_2 lubricating crystal

Nano WS2 crystal is a kind of solid lubrication material with excellent lubrication performance. This paper reports a new method of preparing nano WS2 lubricating crystal using equipment of Mechanical-physical Solid State Reaction Methods (MPSSRM). The phase analyses of nano WS2 lubricating crystal were made in the experiment of XRD. The shift of binding energies from W 4f7/2 and S 2p3/2 electrons for specimens of different diameters was investigated with ESCALAB-MK Ⅱ , and the spectra fitting analysis for S 2p3/2 electron in S-W-S cluster of diameters 50 nm and 10 nm were performed. The results show that the diffraction patterns for WS2 single phase were observed; the pronounced quantum size effect exists in S-W-S nano clusters, and it enhances the hybridization of different electronic shell obits and formed a closed hollow spherical structure without any dangling bond. In the lubricating process, such a system can maintain its chemical stability and decrease energy dissipation.