| 丙烯酰胺和甲基丙烯酸甲酯的原子转移自由基共聚合 |
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| 引用本文： | 廖仲春.丙烯酰胺和甲基丙烯酸甲酯的原子转移自由基共聚合[J].湖南理工学院学报,2004,17(3):91-94. |
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| 作者姓名： | 廖仲春 |
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| 作者单位： | 长沙民政学院 湖南长沙410004 |
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| 摘 要： | 以 MeClPr]/CuBr/Me6TREN]为催化体系 ,采用原子转移自由基法 (ATRP)对丙烯酰胺 (AAm)和甲基丙烯酸甲酯 (MMA)进行了共聚合 ;考察了聚合时间、单体和引发剂配比、聚合温度等因素对聚合的影响 ,合成了分子量分布较窄的无规共聚物。
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| 关 键 词： | 丙烯酰胺 甲基丙烯酸甲酯 原子转移自由基聚合 活性聚合 |
| 文章编号： | 1672-5298(2004)02-0091-04 |
| 修稿时间： | 2004年3月11日 |
Atom transfer radical copolymerization of Acrylamide with Methyl Methacrylate |
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| LIAO Zhong-chun.Atom transfer radical copolymerization of Acrylamide with Methyl Methacrylate[J].Journal of Hunan Institute of Science and Technology,2004,17(3):91-94. |
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| Authors: | LIAO Zhong-chun |
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| Abstract: | The copolymerization of acrylamide(AAm) with methyl methacrylate(MMA) was performed by atom transfer radical polymerization(ATRP).Using MeClPr]/CuBr/Me6TREN] as the initiating/catalyst system in toluene solution.Effects of copolymerization time,ratios of monomer to initiator and rection temperature on copolymerization were studied, It is found that the resulting copolymers possess well-defined molecular weights and low polydispersities. |
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| Keywords: | Acrylamide Methyl Methacrylate Atom Transfer Radical Copolymerization living copolymerization |
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